نتایج جستجو برای: niobium pentachloride
تعداد نتایج: 3282 فیلتر نتایج به سال:
In this study, different samples of Niobium and Vanadium co-doped titania thin films (5-10-15 mol% Nb and 5-10-15 mol% V) were prepared via sol−gel dip coating method, using niobium chloride as niobium precursor, ammonium metavanadate as vanadium precursor, and titanium (IV) butoxide (TBT) as titanium precursor. The effects of doping amount on the structural, optical, and photo-catalytic prope...
An empirical correlation is established for relating Raman stretching frequencies of niobium-oxygen (Nb-O) bonds to their respective bond distances in niobium oxide compounds. The correlation is an exponential least-squares fit between measured Raman frequencies and reported crystallographic bond lengths. Niobium-oxygen bond strengths (in valence units) are also related to Raman stretching freq...
Atomic-scale characterization of hydrogen and formation of niobium hydrides, using ultraviolet (wavelength=355 nm) picosecond laser-assisted local-electrode atom-probe tomography, was performed for ultrahigh purity niobium utilizing different laser pulse energies, 10 or 50 pJ/pulse or voltage pulsing. At 50 pJ/pulse, hydrogen atoms migrate onto the 110 and 111 poles as a result of stimulated su...
Illumination of diamond with above-bandgap light results in emission of electrons into water and formation of solvated electrons. Here we characterize the materials factors that affect that dynamics of the solvated electrons produced by illumination of niobium substrates and of diamond thin films grown on niobium substrates using transient absorption spectroscopy, and we relate the solvated ele...
The decay of (19)O(β(-)) and (19)Ne(β(+)) implanted in niobium in its superconducting and metallic phases was measured using purified radioactive beams produced by the SPIRAL GANIL facility. Half-lives and branching ratios measured in the two phases are consistent within a 1σ error bar. This measurement casts strong doubts on the predicted strong electron screening in a superconductor, the so-c...
The nucleation and growth of niobium pentaethoxide (NPE)-derived clusters in ethanol, through acid-catalyzed hydrolysis/condensation in the presence and absence of the silsesquioxane 1,2-bis(triethoxysilyl)ethane (BTESE), was monitored at 298-333 K by small-angle X-ray scattering. The data were analyzed with a newly derived model for polydisperse mass-fractal-like structures. At 298-313 K in th...
Niobium is one of the major alloying elements, among the refractory elements, contributing to the strengthening of superalloys. Consequently, data about its behavior and its migration mechanism in fcc-Ni are essential knowledge to understand and control the strengthening in such alloys. We present in this work Nb interactions, solubility and diffusion in Ni performed by using the GGA approximat...
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