The characteristics of nanoporous inorganic coatings on implants or on implantable devices are reviewed. The commonly used nanoporous materials, such as aluminum oxide (Al(2)O(3)), titanium oxide (TiO(2)) and porous silicon are highlighted with illustrative examples. The critical issues for sustained release systems are examined and the elution profiles of nanoporous coatings are discussed. The...

Nanoporous metals with bicontinuous ligament-channel structure are of great importance in catalysis, electro-catalysis, actuation and energy storage conversion. However, the intrinsic brittleness nanoporous has always been “Achilles heel” that impedes their practical applications. Utilizing vapor pressure difference metals, herein we propose a flexible general phase alloying (VPA)-dealloying st...

Nanoporous and nonporous three-dimensional silicon nanowire arrays (SiNWAs) prepared with metal-assisted chemical etching method were investigated as photocatalysts in dye photodegradation systematically. In comparison with nonporous SiNWAs, nanoporous SiNWAs have higher surface area, larger pore volume, stronger light absorption and better photocatalytic activity. After the HF-treatment, the p...

Recently discovered synthesis of unusual curved nanoporous silica shapes, such as rods, discoids, spheres, tubes, and hollow helicoids, have brought forth the problem of understanding the formation mechanism. Knowledge of such mechanism may lead to the ability to control the nanoporous shapes. This is important in a variety of applications and new technologies where nanostructure and geometry d...

Magnesiothermic reduction can directly convert SiO2 into Si nanostructures. Despite intense efforts, efficient fabrication of highly nanoporous silicon by Mg still remains a significant challenge due to the exothermic reaction nature. By employing table salt (NaCl) as a heat scavenger for the magnesiothermic reduction, we demonstrate an effective route to convert diatom (SiO2) and SiO2/GeO2 int...

Nanostructured Si as the high efficiency photoelectrode material is hard to keep stable in aqueous for water splitting. Capping a passivation layer on the surface of Si is an effective way of protecting from oxidation. However, it is still not clear in the different mechanisms and effects between insulating oxide materials and oxide semiconductor materials as passivation layers. Here, we compar...

We present the rational synthesis of nanoporous CuS for the first time by chemical dealloying method. The morphologies of the CuS catalysts are controlled by the composition of the original amorphous alloys. Nanoporous Cu2S is firstly formed during the chemical dealloying process, and then the Cu2S transforms into CuS. The nanoporous CuS exhibits excellent photocatalytic activity for the degrad...

In this paper, porous metal−organic frameworks (MIL-53 [CrIII (OH).{O2C-C6H4-CO2}.{HO2C-C6H4-CO2H}x]) were hydrothermally synthesized and, then, a hybrid composite of these synthesized porous metal−organic frameworks (MOF) with acid-treated multi-walled carbon nanotubes (MWCNTs) was prepared. The materials were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), Brunau...

applying nanoporous materials is an appropriate method for improving chemical quality of the water due to high surface area, internal porous structure (porosity), high absorption capability of harmful gases and liquids, and capability of reactivating the surface. therefore, actions were carried out in order to investigate the effect of activated carbon and zeolite on reducing the total dissolve...

Tuning localized surface plasmon resonance (LSPR) of nanoporous metals is crucial to manipulate light within tiny volumes for the implementation of optical devices at the nanoscale. Herein, nanoporous gold-alumina core-shell films with constant gold skeleton and variable alumina sheaths are fabricated by means of chemical corrosion and subsequent atomic layer deposition. Optical transmission pr...