In this paper Mathematica is used to solve the moving boundary problem of freezing in a finite slab for higher order perturbations. Mathematica is a new system which makes it possible to do algebra with computer. More specifically, it enables researchers to find the location of the ice at any time for as high order of perturbation as one whishes. Using of Mathematica and outer solution and an i...

This study aims at investigating the interface between emotion and intonation patterns (more specifically, duration and pitch amplitude of speech). To this end, the acoustic properties of spectral parameters related to speech prosody are investigated. The results of acoustic and Statistical analysis show that mean level and range of FO in the contours vary strongly as a function of the degree o...

In this work we present a set of force fields for nine synthetically relevant and/or structurally interesting N-heterocyclic carbenes, including imidazol-, thiazol-, triazol-, imidazolidin-, and pyridine-ylidenes. The bonding parameters were calculated by using a series of geometry optimizations by ab initio methods. For fitting the non-bonding interactions, a water molecule was employed as a p...

The organocatalytic behavior of N-heterocyclic carbenes in the aerobic oxidation of aromatic aldehydes to esters with boronic acids has been explored. This transition metal-free protocol allows access to a wide variety of aromatic esters in good to excellent yields under mild reaction conditions.