The molybdenum enzymes sulfite oxidase and xanthine dehydrogenase have been investigated by fluorescence-detected EXAFS using synchrotron radiation, and the results have been interpreted with improved EXAFS analysis procedures. A new treatment of EXAFS amplitudes has been developed which allows the extraction of meaningful Debye-Waller factors using experimentally derived functions. A search pr...

The authors have studied the elemental and phase compositions of electric arc coating with a flux-cored wire Fe – C Si Mn Cr Ni Mo system. Formation was carried out using ASAW-1250 welding tractor fabricated on plates made 09G2S steel. Aluminum production gas cleaning dust has been introduced into composition flux cored (instead amorphous carbon). Chemical deposited metal determined by X-ray fl...

Atrazine has been identified in at least 20 of the 1,636 hazardous waste sites that have been proposed for inclusion on the EPA National Priorities List (NPL) (HazDat 2003). However, the number of sites evaluated for atrazine is not known. The frequency for these sites within the United States can be seen in Figure 6-1. Of these sites, all 20 are located within the United States and none are lo...

Molybdenum is an essential element in plants and animals as a cofactor for enzymes. Molybdenum trioxide is used in metallurgical processes, in cosmetics as a pigment, and in contact lens solution, yet limited information is available on molybdenum genotoxicity. In the present study the micronucleus (MN) assay in human lymphocytes and mouse bone marrow and the dominant lethal assay in mice were ...

In this study, a new recoverable catalyst for the epoxidation of olefins was developed using a layered polysiloxane as a support for immobilizing  (salen) molybdenum(VI) complex by electrostatic interaction between the surface of the solid support and the electrically charged molybdenum complex. Characterization of the heterogeneous catalyst by Fourier transform infrared, XRD,1H NMR,...

We investigate the performance of robust estimates of multivariate location under nonstandard data contamination models such as componentwise outliers (i.e., contamination in each variable is independent from the other variables). This model brings up a possible new source of statistical error that we call “propagation of outliers.” This source of error is unusual in the sense that it is genera...

Copper, zinc, selenium, and molybdenum are involved in many biochemical processes supporting life. The most important of these processes are cellular respiration, cellular utilization of oxygen, DNA and RNA reproduction, maintenance of cell membrane integrity, and sequestration of free radicals. Copper, zinc, and selenium are involved in destruction of free radicals through cascading enzyme sys...

A method is described for direct analysis of lead in blood utilizing the carbon rod atomizer. Aliquots of whole blood are analyzed without pre-treatment. Resuits are comparable to those for a similar non-flame technique in which whole blood samples were prediluted with “Triton X-100.” The small sample volumes required and the minimal sample preparation further diminish the possibility of spurio...

fio = atomic transition oscillator strength g = linewidth distribution function, sec We have demonstrated the use of laser-induced flug = energy-averaged Gaunt factor orescence (LIF) to monitor the charge-exchange ion 9i = degeneracy for atomic level i erosion of the molybdenum accelerator electrode in h = Planck's constant, J sec ion thrusters. This real-time, nonintrusive method h = Planck's ...