Bidentate phosphine ligands have been prepared on polystyrene beads modified with polyether dendron spacers. When complexed to Pd(0), these systems exhibited a negative dendritic effect on Heck catalysis (contrary to the analogous monodentate phosphine systems), but mostly a positive influence on carbonylation. This opposite influence of the dendronization falls into line with other differences...

Atomic force microscopy (AFM) imaging of isolated submicron dodecyltrichlorosilane coated silica spheres, immobilized at the liquid polystyrene- (PS-) air interface at the PS glass transition temperature, T(g), allows for determination of the contact angle θ versus particle radius R. At T(g), all θ versus R measurements are well described by the modified Young's equation for a line tension τ = ...

We designed and fabricated a centrosymmetric material where one may be able to consider an efficient quadratic nonlinear interaction. We followed a solid phase-supported organic synthesis methodology to covalently bind a large number of highly nonlinear molecules to the surface of polystyrene nanospheres. Such chemically modified optically nonlinear latex spheres, when suspended in water, are s...

In this work the reliability of the focused-ion-beam (FIB) patterning on polystyrene (PS) colloidal crystals at different scales is determined. Ordered arrays of PS spheres (465 nm) are successfully modified by selectively removing a single sphere. The water-vapor assisted FIB milling is crucial to obtain this result. Furthermore, isolated PS spheres are FIB drilled with or without chemically e...

The interaction of nanoscaled materials with biological systems is currently the focus of a fast-growing area of investigation. Though many nanoparticles interact with cells without acute toxic responses, amino-modified polystyrene nanoparticles are known to induce cell death. We have found that by lowering their dose, cell death remains low for several days while, interestingly, cell cycle pro...

Using a self-assembly double template method, we have prepared highly ordered magnetic dot arrays of Ni on submicron scales. For the template preparation we have used colloidal suspensions of polystyrene latex spheres with different diameters ranging from 200 to 700 nm combined with secondary templates of the conducting polymer polypyrrole. By variation of the template parameters and the deposi...

The blending effect of poly maleic anhydride-styrene-methyl methacrylate (MA-St-MMA) terpolymer on non-miscible PVC and Polystyrene was studied depending their thermomechanical properties. Depending the amount synthesized used compatibilizer tensile strength, modulus, properties blends are enhanced. unmodified with small amounts exhibit two-step degradation whereas those containing 6, 8 10 perc...

in this study, polystyrene ethylene butylene polystyrene (psebs) was functionalized to prepare mono and bipolar ion exchange membranes. in the case of the bipolar membrane, platinum was used as the intermediate layer. nacl solution of concentration ranging from 5 g/l to 25 g/l was used as the feed solution. a commercially procured ion exchange membrane made of polystyrene divinyl benzene was al...

The high molecular weight poly (ethylene oxide) was used to synthesize telechelic bromine terminated poly (ethylene oxide) polymers. The low molecular weight polystyrene anion was generated by living anionic polymerization by controlling monomer/initiator ratio. The living polystyrene anion was reacted with telechelic bromine terminated poly (ethylene oxide) polymers to obtain water soluble pol...

We have used novel microporous biphenylene-pillared layered silicates as receptors in a quartz crystal microbalance (QCM) for sensing toluene vapors. The silicate was successfully coated on a QCM electrode modified with 2-aminoethanethiol. The resultant electrode showed quantitative frequency responses due to enhanced adhesion between the silicate and the electrode. The silicate-coated electrod...