The crystal structures of natural (Mt. Koashva, Khibiny alkaline massif, Kola Peninsula, Russian Arctic) and synthetic (obtained from an aqueous solution sodium phosphate fluoride (1:1) by evaporation at room temperature (RT)) natrophosphate, Na7(PO4)2F·19H2O, have been investigated using single-crystal X-ray diffraction analysis. Natrophosphate its analogue are cubic, Fd-3c, a = 27.6942(3) Å (...