Metal–dithiolene complexes form very attractive categories of molecular metals and superconductors. They can have various oxidation states and can range from electron acceptors to donors. The first observation of metallic behavior in crystalline metal– dithiolene complexes was reported for Li0.75[Pt(mnt)2]?2H2O [mnt~maleonitriledithiolate; Scheme 1] by Underhill et al. in 1981. The conduction p...

the mono-metallic and bi-metallic catalysts have been prepared by impregnating with solutions containing a compound of h2ptcl6,wo3 and 1ml hcl (0.1 mol). it should be noted that the catalysts’ activity and selectivity have been determined under these conditions : 450-5000c ,and 15-25atm by h2. for converting n-heptane , the molar ratio h2/c7h16 is 5 , and lhsv is 1.5ml/h. it has been proved tha...

a  new  type  of  cation-exchange  nanocomposite  membranes  was prepared  by  in-situ  formation  of  zno  nanoparticles  in  a  blend containing  sulfonated  poly  (2,6-dimethyl-1,4-phenylene  oxide)  and sulfonated polyvinylchloride  via  a  simple  one-step  chemical method.  as-synthesized  nanocomposite  membranes were characterized  using  fourier  transform  infrared  spectroscopy, scan...

In this study, the effect of different parameters such as time and temperature of calcination and milling on the formation of calcium aluminosilicates was investigated. Raw materials used in this study were calcium carbonate and kaolin in high purity. Powder X-ray diffraction patterns were obtained from all samples after heat treatment at various temperatures and times. To study the microstruct...

introduction: foreign body aspiration (fba) represents a life-threatening emergency .it occurs primarily in children below 3 years. generally, the most common aspirated fb is organic material such as nuts or beans. sharp foreign bodies (fbs) are of particular concern to the attending clinician, because of their potential to perforate the air passage and cause possible complications. here in, we...

A metallic taste is reported by cancer patients as a side effect of systemic therapy. Despite the high prevalence, this taste alteration has received limited attention. The present study investigated: 1) the prevalence of metallic taste in cancer patients treated with systemic therapy; 2) possible predictors of metallic taste; and 3) characteristics of metallic taste. A heterogeneous population...

The magnitude of ionic conductivity is known to depend upon both mobility and number available carriers. For proton conductors, hydration a key factor in determining the charge–carrier concentration ABO3 perovskite oxides. Despite high reported calcium titanate (CaTiO3), this has thus far been regarded as poor conductor due low capability. Here, enhanced defective Ca0.92TiO2.84(OH)0.16 prepared...

The deep interiors of Jupiter and Saturn consist of fluid, metallic hydrogen. In Jupiter the metallic hydrogen is uniformly mixed with helium. In Saturn, the incomplete solubility of helium may cause unmixing and energy release. In the interiors of Uranus and Neptune the fluid mixture (of hydrogen, helium, water, methane and ammonia) is metallic or ionic. The terrestral planetary cores are pred...

A route for systematically accessing the oxo atoms of linear uranyl (UO22+) cation via cation–cation and halogen bonding interactions is detailed, interaction strengths are probed structural, vibrational, computational means.

Transformation optics offers an unconventional strategy to the design of metamaterial devices. In this letter, we propose a class of optical transformation media, illusion media, which can render the enclosed object invisible and generate one or more virtual objects as desired. An arbitrary object enclosed by such an illusion medium layer appears to be one or more other objects. We apply the pr...