Stabilty constant of binary complexes of Fe(III) and Mn(II) with medicinally important ligand chloramphenicol antibiotics in solution were determined by paper electrophoretic technique. Stability constant of the complexes were determined at 25°C temperature and 0.1M (HClO4) ionic strength. Our study is based upon the migration of a spot of metal ions on a paper strip at different pH against mob...

A BSTRACT: A review is given of the application of ESR spectroscopy to the study of hydrated transition metal ions and nitroxide spin probes in the interlamellar region of smectites and vermiculites. These investigations have not only provided information regarding the structure and mobility of the intracrystalline water-cation layers but have also demonstrated the reactivity and catalytic prop...

Articles you may be interested in Single crystalline Sc 2 O 3 / Y 2 O 3 heterostructures as novel engineered buffer approach for GaN integration on Si (111) Growth of high crystalline quality semi-insulating GaN layers for high electron mobility transistor applications Growth stresses and cracking in GaN films on (111) Si grown by metal-organic chemical-vapor deposition. I. AlN buffer layers

Studies of low-frequency resistance noise show that the glassy freezing of the two-dimensional (2D) electron system in the vicinity of the metal-insulator transition occurs in all Si inversion layers. The size of the metallic glass phase, which separates the 2D metal and the (glassy) insulator, depends strongly on disorder, becoming extremely small in high-mobility samples. The behavior of the ...

In this study, we demonstrate the stability of highLa2O3 metal–insulator–metal (MIM) capacitors under constant voltage stress (CVS). It was found that the variation in capacitance caused by CVS strongly depends on the injected charges regardless of stress biases. Furthermore, the quadratic voltage coefficient of capacitance ( ) decreases with a logarithmic increase in dielectric loss. Charge tr...

Ion mobility studies and density functional theory calculations were used to study the structures of [Zn/diethylenetriamine/Hexose/Cl]+ complexes in an effort to probe differences in the three-dimensional conformations. This information allows us to gain insight into the structure of these complexes before collisional activation, which is the first step in understanding the stereoselective diss...

The binding of carbohydrate substrates to concanavalin A (Canavalia ensiformis agglutinin (ConA)) is essential for its interaction with various glycoproteins. Even though metal ions are known to control the sugar binding ability of legume lectins, the interplay between sugar and metal ion binding to ConA has not been elucidated in a detailed manner at the atomic level. We have carried out long,...

The relative permeability of endplate channels to monovalent and divalent metal ions was determined from reversal potentials. Thallium is the most permeant ion with a permeability ratio relative to Na+ of 2.5. The selectivity among alkali metals is weak with a sequence, Cs+ greater than Rb+ greater than K+ greater than Na+ greater than Li+, and permeability ratios of 1.4, 1.3, 1.1, 1.0, and 0.9...