The temperature dependence of the structure water confined in hydrophilic mesostructured porous silica (MCM-41) and hydrophobic benzene-bridged periodic mesoporous organosilicas (PMOs) is studied by Raman vibrational spectroscopy. For capillary filled pores (75% relative humidity, RH), OH stretching region dominated contribution from liquid situated core part pore. It adopts a bulklike that mod...

A zirconium modified MCM-48 mesoporous material was synthesized by surfactant-templated method. Surface grafting Zr-MCM-48 with tungstophosphoric acid led to a great enhancement of both the number of the Brønsted acid sites and acidity strength in comparison with the bare support. At 100 ̊C, the 30 wt% H3PW12O40/Zr-MCM-48 contained 174 mol/g Brønsted acid sites which were 21.7 times greater tha...

We have used Monte Carlo simulations to study the formation of the MCM-41 mesoporous silica material, with a new lattice model featuring explicit representations of both silicic acid condensation and surfactant self-assembly. Inspired by experimental syntheses, we have adopted the following two-step "synthesis" during our simulations: (i) high pH and low temperature allowing the initial onset o...

Benzene was hydroxylated with hydrogen peroxide (H2O2) in the presence of catalytic amounts of copper complexes in acetone to yield phenol at 298 K. At higher temperature, phenol was further hydroxylated with H2O2 by catalysis of copper complexes to yield p-benzoquinone. The kinetic study revealed that the rate was proportional to concentrations of benzene and H2O2, but to the square root of co...

Morphology-controlled nanomaterials such as silica play a crucial role in the development of technologies for addressing challenges in the fields of energy, environment, and health. After the discovery of Stöber silica, followed by that of mesoporous silica materials, such as MCM-41 and SBA-15, a significant surge in the design and synthesis of nanosilica with various sizes, shapes, morphologie...