In article number 2002753, Lirong Zheng, Aijuan Han, Junfeng Liu and co-workers report the development of a manganese single-atomic-site catalyst anchored on porous nitrogen-doped carbon with Mn-N4 structure, which exhibits superior electrocatalytic activity stability for alkaline oxygen reduction reaction (ORR) in zinc-air batteries. Furthermore, operando XAFS is applied to uncover mechanism u...