The structure and luminescence properties of a well-known trinuclear Au(i) imidazolate complex are determined for the first time along with its interaction with the organic π acid perfluoronaphthalene in the solid state and solution.

The upconversion luminescence properties of Yb3+/Tm3+-codoped oxyfluoride tellurite glasses under 980 nm excitation are investigated experimentally. The intense blue and relatively weak red emissions centered at 475 and 649 nm corresponding to the transitions G4 → H6 and 1

A luminescent cyclometalated platinum(II) complex has been shown to sandwich a silver ion, which demonstrates intense luminescence with appreciable photoluminescence quantum yield. Computational studies have been performed to provide insights into the nature of the photophysical properties.

A plasmid containing a transcriptional fusion of the Escherichia coli katG promoter to a truncated Vibrio fischeri lux operon (luxCDABE) was constructed. An E. coli strain bearing this plasmid (strain DPD2511) exhibited low basal levels of luminescence, which increased up to 1,000-fold in the presence of hydrogen peroxide, organic peroxides, redox-cycling agents (methyl viologen and menadione),...

We report on the influence of doping, temperature, porosity, band gap, and oxidation on the photoluminescence ~PL! properties of anodically etched porous a-Si:H and a-Si:C:H thin films. Only boron-doped, p-type a-Si:H samples exhibited visible photoluminescence. Two broad PL peaks at ;1.6 and ;2.2 eV are apparent in room temperature PL spectra. The intensity of the 2.2 eV peak as well as the na...

Solution-processed hybrid perovskite of CH3NH3PbI3 (MAPbI3) exhibits an abnormal luminescence behavior at around the tetragonal-orthorhombic phase transition temperature. The combination of time resolved photoluminescence (PL), variable excitation power PL, and variable-temperature X-ray diffraction (XRD) allows us to clearly interpret the abnormal luminescence features in the phase transition ...

The coupling between localized surface plasmons (LSPs) within silver nanostructures and excitons in a silicon-rich silicon nitride (SiNx) matrix has been demonstrated via the Purcell effect. A simple model is employed for the estimation of the Purcell factor as well as the average position of excitons within a luminescence matrix. The estimated average position of the excitons is located at app...

A series of NaLuF4-based hexagonal phase upconversion nanocrystals (UCNs) were synthesized by a facile solvothermal method and the properties of the UCNs were investigated. The results show that the as-prepared nanocrystals exhibit pure hexagonal lattice structures, uniform morphologies, high monodispersities and excellent upconversion luminescence. The upconversion luminescence (UCL) intensiti...

We perform an optical study of sulforhodamine B and sulforhodamine 101 molecules solved in water droplets ~reversed micelles! that are stabilized by a surfactant and suspended in various mixtures of heptane and toluene. While the dielectric permittivity of the surrounding medium varies with the proportions of heptane and toluene, the chemical environment of the dye molecules always remains the ...

We report a novel ytterbium complex [Yb(tta)3DFQZ] which exhibited obviously enhanced two-photon sensitized near-infrared luminescence properties of Yb(3+) compared to the usually reported Yb(3+) complexes, with a two-photon excitation action cross-section of 22 GM under excitation at 860 nm at 298 K. Unlike other lanthanide complexes, [Yb(tta)3DFQZ] under nitrogen exhibited quantum yields for ...