A microscopic model of a lithium battery is developed, which accounts for lithium diffusion within particles, transfer of lithium from particles to the electrolyte and transport within the electrolyte assuming a dilute electrolyte and Butler–Volmer reaction kinetics. Exploiting the small size of the particles relative to the electrode dimensions, a homogenised model (in agreement with existing ...

Exploring advanced high-rate anodes is of great importance for the development of next-generation high-power lithium-ion batteries (LIBs). Here, novel carbon nanotubes (CNTs)/Li4Ti5O12 (LTO) core/shell arrays on carbon cloth (CC) as integrated high-quality anode are constructed via a facile combined chemical vapor deposition-atomic layer deposition (ALD) method. ALD-synthesized LTO is strongly ...

A bilayered cellulose-based separator design is presented that can enhance the electrochemical performance of lithium-ion batteries (LIBs) via the inclusion of a porous redox-active layer. The proposed flexible redox-active separator consists of a mesoporous, insulating nanocellulose fiber layer that provides the necessary insulation between the electrodes and a porous, conductive, and redox-ac...

Nanostructured LiFePO4 (LFP) electrodes have attracted great interest in the Li-ion battery field. Recently there have been debates on the presence and role of metastable phases during lithiation/delithiation, originating from the apparent high rate capability of LFP batteries despite poor electronic/ionic conductivities of bulk LFP and FePO4 (FP) phases. Here we report a potentiostatic in situ...

In view of severe changes in temperature during different seasons in cold areas of northern China, the decay of battery capacity of electric vehicles poses a problem. This paper uses an electric bus power system with semi-active hybrid energy storage system (HESS) as the research object and proposes a convex power distribution strategy to optimize the battery current that represents degradation...

Phase transitions in Li-ion electrode materials during (dis)charge are decisive for battery performance, limiting high-rate capabilities and playing a crucial role in the cycle life of Li-ion batteries. However, the difficulty to probe the phase nucleation and growth in individual grains is hindering fundamental understanding and progress. Here we use synchrotron microbeam diffraction to disclo...