Boehm and Martire have shown that the Flory-Huggins (FH) lattice model applied to mixtures of squares and rigid rods in solvent on a two dimensional lattice gives different results depending on whether rods or squares are placed first onto the lattice. This correct derivation places the validity of the FH model itself into question since the final result should be independent of the order of pl...

Polypropylene owing to its apolar nature suffers from compatibility problems with clay, which is partially polar even after the surface modification with alkyl ammonium ions. To circumvent this limitation, polypropylene nanocomposites have been synthesized by using two methodologies: a) partial polarization of the matrix by the addition of low molecular weight compatibilizer which owing to its ...

PURPOSE Calcium-silicate cements have been recently proposed for application in dentistry as root-end filling and root-perforation repair materials. The aim of this study was to investigate the effect of ageing of experimental calcium-silicate cements on the chemistry, morphology and in vitro bioactivity of the surface, as well as on osteoblast viability and proliferation. METHODS Two experim...

partial least squares modeling as a powerful multivariate statistical tool was applied tothe simultaneous spectrophotometric determination of silicate and phosphate in aqueoussolutions. the concentration range for silicate and phosphate were 0.02-0.6 and 0.4-3 μg ml-1,respectively. the experimental calibration set was composed with 30 sample solutions using amixture design for two component mix...

Thermal and antimicrobial properties of hybrid synthesized compounds were evaluated in thepresent study. Hybrid structures were synthesized via two main organic and inorganic components,namely: 2-Mercaptobenzothiazole (MBT) and sodium Montmorillonite clay (Na+-MMT). The synthesis process took place in a direct reaction, intercalation; and the resultingmaterial was characterized. Results of scan...

Introduction Poly(urethane urea) multiblock copolymers [PUU] are used in variety of biomedical applications, including as blood-contacting components in ventricular assist systems. One of the drawbacks of these materials (particularly when used in completely implantable devices) is their relatively high permeability to air and moisture. Conventional biomedical PUU elastomers are generally compo...

Original graphene oxide (GO) nanosheets were prepared using the Hummers method and found to easily aggregate in aqueous and cement composites. Using carboxymethyl chitosan (CCS) as a dispersant, few-layered GO nanosheets (1-2 layers) were obtained by forming CCS/GO intercalation composites. The testing results indicated that the few-layered GO nanosheets could uniformly spread, both in aqueous ...

A layered silicate, KHSi2O5, was synthesized via a hydrothermal method using an amorphous silicon dioxide (SiO2) block, which is industrial waste. This silicate used as host compound for ion-exchange reactions with Ag+ and Cu2+ ions, the antibacterial properties of ion-exchanged compounds were investigated. The crystal structures retained during reaction; however, in case Cu2+, small amount Cu(...