The present paper reports a spectroscopic and kinetic study of the reaction with oxygen and carbon monoxide of (a) the abnormal hemoglobin Zürich (beta 63, E7 His leads to Arg), (b) its isolated abnormal chains (beta ZH), and (c) a reconstituted hybrid containing cobalt instead of iron on the normal alpha chains (Co alpha)2-(Fe beta ZH)2. The abnormal beta ZH chains, isolated from hemoglobin Zü...

Catalytic activity of catalase (CAT, EC 1.11.1.6), immobilized on carbon black NORIT and soot PM-100, with respect to decomposition of dibenzoyl peroxide (BPO) in non-aqueous media (acetonitrile and tetrachloromethane), was investigated with a quantitative UV-spectrophotometrical approach. Progress of the above reaction was controlled by selected kinetic parameters: the apparent Michaelis const...

The measurements of the overall bicyclic peroxy radical + NO rate constant for the 1,3,5-trimethylbenzene (1,3,5-TMB) system and of the nitrate product yields for the benzene, toluene, p-xylene, and 1,3,5-TMB systems were performed via the turbulent flow chemical ionization mass spectrometry technique. While the overall rate constant was found to be consistent with the value used in the most de...

This paper studies several kinetic aspects of flotation of celestite and calcite in a mechanical cell with sodium dodecylsulphate as the collector agent, using pure minerals ranging in average particle size between 137 and 74 mm, respectively, with a constant pH 3 in the flotation bath in all experiments. The results obtained indicate that both minerals float rapidly and that the flotation rate...

The 2D projection of a rotating Necker cube yields an ambiguous 3D interpretation based on both 2D shape and kinetic depth information. The present study shows that the alternation rate of the two 3D interpretations is constant with the rotation speed up to some critical value (around 25 turns/min for a cube whose sides subtend 2.5 deg) and increases monotonically thereafter. It is proposed tha...

Despite the fact that there are wastewater treatment plants (WWTPs) currently operational across Iran and great advances have been made in this area, there are still problems in the design, construction, and operation of WWTPs with large nonlinear systems, varying flow rates, and pollution charges. The objective of this study was to investigate the effect of operating parameters including the r...

Biodegradation offers an eco-friendly option for disposal of waste coming from different breweries and wineries. A model-based analysis through rigorous experimentation has been accomplished to study different aspects of the biodegradation of distillery wastes. Using distillery waste as resource material, energy is derived in the form of biogas containing high percentage of methane which is pro...

The sensitivity of molecular vibrational population dynamics, governing the CO laser operated in fundamental and overtone transitions, to vibration-tovibration rate constants is investigated. With this aim, three rate constant sets have been used, differing in their completeness (i.e. accounting for singlequantum exchange only, or for multi-quantum exchange with a limited number of rate constan...

Vesicles formed from synthetic, double-tailed amphiphiles are often used as mimics for biological membranes. However, biological membranes are a complex mixture of various compounds. In the present paper we describe a first attempt to study the importance of additives on vesicular catalysis. The rate-determining deprotonation of 5-nitrobenzisoxazole (Kemp elimination) by hydroxide ion is effici...