Understanding anion adsorption mechanisms is necessary to allow prediction of anion adsorption behavior. This study was conducted to evaluate the ability of the triple layer model, a chemical surface complexation model, to describe the effect of changes in solution ionic strength (0.01-1.0 M NaCl) and solution pH (3-11) on B adsorption by the iron oxide, goethite, the aluminum oxide, gibbsite, ...

Most ice in nature forms because of impurities which boost the exceedingly low nucleation rate of pure supercooled water. However, the microscopic details of ice nucleation on these substances remain largely unknown. Here, we have unraveled the molecular mechanism and the kinetics of ice formation on kaolinite, a clay mineral playing a key role in climate science. We find that the formation of ...

[1] We report results on the effects of porewater pH and transients in porewater flow on the deposition and mobilization of colloid-sized clay particles within unsaturated sand columns. The deposition rates of illite under steady-flow conditions were essentially independent of pH, while the deposition rates of kaolinite nearly doubled as the pH decreased from 7.4 to 4.6. Mobilization of kaolini...

Disclaimer The contents of this report reflect the views of the author(s), who are responsible for the facts and the accuracy of information presented herein. This document is disseminated under the sponsorship of Anisotropy is an inherent property of soils. The anisotropy could either be induced by applied stress or inherent from particle eccentricity and preferential deposition. Other than st...

Carbon nanotubes are often modified to be stable in the aqueous phase by adding extensive hydrophilic surface functional groups. The stability of such CNTs in water with soil or sediment is one critical factor controlling their environmental fate. We conducted a series of experiments to quantitatively assess the association between water dispersed multi-walled carbon nanotubes (MWCNTs) and thre...

The removal mechanisms of silicate using an aluminum hydroxide co-precipitation process was investigated and compared with an adsorption process, in order to establish an effective and validated method for silicate removal from wastewater. Adsorption isotherms, XRD and FT-IR analyses showed that silicate uptake occurred by adsorption to boehmite for initial Si/Al molar ratios smaller than two, ...

-The adsorption of Ni(II) and Cu(II) on to the clay minerMs kaolinite, chlorite, and illite has been investigated. The quantity of Ni(II) at pH 6 and Cu(II) at pH 5 adsorbed has been found to vary in the manner chlorite > illite > kaolinite. Examination of the mode of bonding of the metal ions to the clay minerals using X-ray photoelectron spectroscopy (XPS) has been carried out. Comparison of ...