Solution-phase self-assembly of nanocrystals into mesoscale structures is a promising strategy for constructing functional materials from nanoscale components. Liquid environments are key to self-assembly since they allow suspended nanocrystals to diffuse and interact freely, but they also complicate experiments. Real-time observations with single-particle resolution could have transformative i...

Dynamic behaviors are abundant in field-responsive colloidal suspensions. Being beyond the usual point-dipole approximation, we develop a multiple image method of dipoles for two dynamic unequal colloidal dielectric spherical particles, which can be perfectly reduced to those for two static conducting particles. The method is applied to investigate colloidal electric interparticle forces under ...

Abstract Different from previous discrete element methods (DEM), where irregular 3D particle shapes are approximated by subspheres, vertices, or voxels, this study aims to develop an innovative and computationally effective DEM method directly employing spherical harmonic functions for simulations of irregular‐shaped particles. First, the surface points a represented with only limited number co...

A general method for computing the hydrodynamic interactions among N suspended particles, under the condition of vanishingly small particle Reynolds number, is presented. The method accounts for both near-field lubrication effects and the dominant many-body interactions. The many-body hydrodynamic interactions reproduce the screening characteristic of porous media and the ‘effective viscosity ’...

Thermal treatment of self-assembled FePt nanoparticles reduces the interparticle distances, resulting in dramatic changes in the type and strength of interparticle interactions. Consequently, magnetic properties such as the hysteresis and magnetization reversal mechanisms are strongly affected. It is suggested that controlled annealing of self-assembled nanoparticles may offer a novel approach ...

We present a theoretical formalism based on fluctuational electrodynamics and the Maxwell-stress tensor for describing impact of radiative multiple reflections corrections van der Waals force between two nanoscale spherical particles pair atoms in dipolar approximation. Particularly, we examine forces metallic whose dielectric constant is represented by Drude model, which their material respons...