An innovative methodology for the preparation of high-performance polyolefin-based materials combining a unique dendrimeric silica carrier, straightforward in situ supporting procedure and ethylene polymerization technique was developed.

a series of polystyrene hybrid nanocomposites have been fabricated with varying amounts of tio2 viz., 0, 0.5 and 1 % w/w along with 3% ts by in-situ polymerization method. the influence of surface modified tio2 nanoparticles on the thermal properties of ps matrix was examined using thermogravimetry and differential scanning calorimetry. thermal characteristics of the polystyrene/ts/tio2 hybrid ...

N-vinylcarbazole (NVK) is proposed as an additive for acrylates thermal free radical polymerization (FRP) and epoxy thermal ring opening polymerization (ROP) at room temperature. The new initiating systems are based on a silane/silver salt/N-vinylcarbazole interaction, which ensures good to excellent polymerization. Moreover, the polymerization is much more efficient under air than under argon....

Poly(anthraquinonyl sulfide) (PAQS)/graphene sheets (GSs) composite was synthesized through in situ polymerization to evaluate its performance as an electrode material for electrochemical capacitors. PAQS was successfully synthesized in the presence of GSs with uniform distribution. PAQS/GSs showed a pair of reversible redox peaks at around 0 V (vs. Ag/AgCl). The specific capacitance of PAQS/GS...

High throughput screening (HTS) of a 205 member Schiff base salicylaldimine ligand library derived from salicylaldehydes bearing bulky ortho-substituents, i.e., 9-anthracenyl, 1,4,5,8-tetramethylanthracenyl or triptycenyl, reacted in-situ with (p-tolyl)CrCl2(thf)3, identified two new classes of highly active chromium based systems for the oligomerization and polymerization of ethylene, respecti...

This study demonstrates the preparation, structure, and properties of polymer-impregnated wood (PIW) based on novel Muchelia macclurei wood through the in-situ polymerization of vinyl and functional monomers. Mixed monomers of glycidyl methacrylate (GMA) and ethylene glycol dimethacrylate (EGDMA) (2:1 molar ratio) were effectively vacuum/pressure impregnated into the cellular structure of the f...

Vertical phase separation of the donor and the acceptor in organic bulk heterojunction solar cells is crucial to improve the exciton dissociation and charge transport efficiencies. This is because whilst the exciton diffusion length is limited, the organic film must be thick enough to absorb sufficient light. However, it is still a challenge to control the phase separation of a binary blend in ...

A multi-hierarchical porous polyaniline (PANI) composite which could be used in good performance pressure sensor and adjustable sensitivity gas sensor has been fabricated by a facile in situ polymerization. Commercial grade sponge was utilized as a template scaffold to deposit PANI via in situ polymerization. With abundant interconnected pores throughout the whole structure, the sponge provided...

polyvinyl ester green composites were synthesized with walnut shell powder (wsp) by in-situ polymerization technique. the green composites have been evaluated for mechanical properties such as tensile strength, tensile modulus and hardness. sliding wear loss, specific wear rate and coefficient of friction were investigated by using computerized pin-on–disc machine at normal applied loads of 20,...

A series of polystyrene hybrid nanocomposites have been fabricated with varying amounts of TiO2 viz., 0, 0.5 and 1 % w/w along with 3% TS by in-situ polymerization method. The influence of surface modified TiO2 nanoparticles on the thermal properties of PS matrix was examined using thermogravimetry and differential scanning calorimetry. Thermal characteristics of the polystyrene/TS/TiO2 hybrid ...