Two new perylene bisimide (PBI) derivatives possessing crown ether receptors at the 1,7 bay-positions and solubilizing ionic imide substituents were synthesized and their self-assembly properties in the presence of different metal ions were studied, revealing highly selective barium ion templated self-assembly of 15-crown-5 functionalized PBI into H-type dimer aggregates.

Ultrafast recombination observed from several perylene imide sensitizers bound to NiO appears to align with Marcus normal region behaviour; this indicates recombination to intra-bandgap states.

2-Amino-2-seleno-5,5-dimethyl-1,3,2-dioxaphosphorinane reacts with acyl chlorides (4-chlorobenzoyl chloride or pivaloyl chloride) yielding the respective N-acyl selenophosphoramides. These derivatives do not isomerise to the related selenocarbonyl imides. X-ray study of N-(4-chlorobenzoyl)-2-amino-2-seleno-5,5-dimethyl-1,3,2-dioxaphosphorinane indicates that the selenium atom is placed in the e...

Up to now, the synthesis of quinazolinones has required lengthy synthetic procedures. Here, we describe an innovative one-pot multicomponent reaction leading to highly substituted quinazolinones. We believe that this novel transformation may open the door for the generation of new and pharmacologically active quinazolinones, but, most important of all, the resurrection of the imide-Ugi scaffold...

In the title compound, C18H18ClNO4, the imide group with its two alkyl substituents is approximately perpendicular to the plane of the naphtho-quinone ring system [dihedral angle = 78.5 (1)°]. Further, the imide carbonyl groups are oriented in an anti sense. In the crystal, the substituted naphtho-quinone rings form π-π stacks in the a-axis direction [perpendicular centroid-centroid distance = ...

0022-2860/$ see front matter 2011 Elsevier B.V. A doi:10.1016/j.molstruc.2011.04.016 ⇑ Corresponding author. E-mail address: [email protected] (O.V. Dipole moments (l), molar Kerr constants (mK) and molecular polarizabilities of several five-membered ring imides and a number of model compounds were measured. Various models for determination of molecular polarizability and mK values wer...