In order to reduce the current costs associated with carbon capture technologies, novel materials such as zeolites and metal-organic frameworks that are based on microporous networks are being studied. We have developed a GPU code that can characterize and screen a large database of zeolite structures and help identify the most e cient structures for carbon capture. The interactions between the...

A quartz crystal microbalance (QCM) was utilized to measure the water content in ethanol. For the improvement of measurement sensitivity, the QCM was modified by applying zeolite particles on the surface with poly(methyl methacrylate) (PMMA) binder. The measurement performance was examined with ethanol of 1% to 5% water content in circulation. The experimental results showed that the frequency ...

The aim of this study was to prepare and characterize a potential drug support system based on surfactant/zeolite composites for anti-inflammatory drugs. In order to increase the adsorbing capacity the external surface of the natural zeolite clinoptilolite was modified with benzalkonium chloride in the treatments raging from 100% to 300% of the zeolite external cation exchange capacity. Adsorpt...

We investigated the reaction mechanism of a metal-unloaded zeolite-plasma hybrid system for decomposition of toluene at room temperature. Short-lived radicals and fast electrons did not contribute substantially to the reaction mechanism of toluene decomposition in the zeolite-plasma hybrid system. The main factor enhancing the reaction mechanism was gas-phase O3 directly reacting with toluene a...

Zeolite (NaX, NaX-CeO2) and mixed oxide (Co4MnAl, NiMgMn) catalysts were tested in catalytic oxidation of volatile organic compounds (VOCs). The different kinds of catalysts proved remarkable activity in catalytic oxidation of ethanol and isopropanol respectively. The deepen comparison revealed that basic zeolite NaX-CeO2 is more suitable for oxidation of isopropanol while oxidation of ethanol ...

Hierarchical ZSM-5 zeolite is hydrothermally synthesized in a single step with cetyltrimethylammonium (CTA) hydroxide acting as mesoporogen and structure-directing agent. Essential to this synthesis is the replacement of NaOH with KOH. An in-depth solid-state NMR study reveals that, after early electrostatic interaction between condensed silica and the head group of CTA, ZSM-5 crystallizes arou...

The relative contributions of external and intracrystalline acidic sites of small pore H-RHO zeolite for the selective synthesis of methylamines from methanol and ammonia have been studied. Nonselective surface reactions which produce predominantly trimethylamine can be eliminated by "capping" the external acidic sites with trimethylphosphite (TMP) and other reagents, thus improving the selecti...

Diels-Alder cycloaddition between cyclopentadiene and p-benzoquinone has been studied in the confined space of a pure silica zeolite Beta and the impact on reaction rate due to the concentration effect within the pore and diffusion limitations are discussed. Introduction of Lewis or Brønsted acid sites on the walls of the zeolite strongly increases the reaction rate. However, contrary to what o...

Background & Aims of the Study:  Nitrate is one of the most important pollutants that its reduced form, nitrite, can cause serious problems for human health and environment. Adsorption with cheap sorbents such as Zeolite is the best way for removal of this pollutant. So this study aimed to apply modified Clinoptilolite Zeolite for nitrate removal. Materials & Methods...

Batch and column experiments were conducted to evaluate the efficiency of a clinoptilolite zeolite as an inexpensive sorbent material to remove cationic surfactant from water. With an initial surfactant concentration greater than its critical micelle concentration, the removal of surfactant is achieved by admicellar sorption onto the zeolite surface. Although the sorption capacity of hexadecylt...