Knowledge of the chemical speciation platinum and solubility Pt-bearing minerals in hydrothermal fluids is required to assess Pt transport, remobilization concentration Earth’s crust. In this study, we combined PtS(s) measurements a reactor allowing fluid sampling, situ X-ray absorption spectroscopy, first-principles molecular dynamics simulations systematically investigate structure, compositi...

Warm fluids emanating from hydrothermal vents can be used as windows into the rocky subseafloor habitat and its resident microbial community. Two new vent systems on the Mid-Cayman Rise each exhibits novel geologic settings and distinctively hydrogen-rich vent fluid compositions. We have determined and compared the chemistry, potential energy yielding reactions, abundance, community composition...

The subseafloor at the mid-ocean ridge is predicted to be an excellent microbial habitat, because there is abundant space, fluid flow, and geochemical energy in the porous, hydrothermally influenced oceanic crust. These characteristics also make it a good analog for potential subsurface extraterrestrial habitats. Subseafloor environments created by the mixing of hot hydrothermal fluids and seaw...

Studies of the Fe, Cu, and Zn isotopic compositions volcanic rocks sulfides provide an important tool for understanding magmatic, hydrothermal, alteration processes, thereby enabling determination both transition metal sources quantification petrologic environmental impacts hydrothermal activities. In this study, δ56Fe δ57Fe values mid-ocean ridge basalts (MORBs) are higher than those seafloor ...

Carbonates. The dominant aqueous deposits in ALH 84001 are carbonate minerals, which form ellipsoids, discs, and other space-filling shapes, Figure 1 [1,4,5,6 etc]. These deposits are chemically zoned, nearly continuously from calcitic and ankeritic cores to magnesite-siderite compositions ranging from nearly pure magnesite to ~Mg45Fe45Ca10 (Fig. 2); hydromagnesite is not reported. The carbonat...

Iron is the most important metal for modern industry and Sweden is by far the largest iron-producer in Europe, yet the genesis of Sweden's main iron-source, the 'Kiruna-type' apatite-iron-oxide ores, remains enigmatic. We show that magnetites from the largest central Swedish 'Kiruna-type' deposit at Grängesberg have δ(18)O values between -0.4 and +3.7‰, while the 1.90-1.88 Ga meta-volcanic host...

The composition of non-methane organic volatile compounds (VOCs) determined in 139 thermal gas discharges from 18 different geothermal and volcanic systems in Italy and Latin America, consists of C(2)-C(20) species pertaining to the alkanes, alkenes, aromatics and O-, S- and N-bearing classes of compounds. Thiophenes and mono-aromatics, especially the methylated species, are strongly enriched i...

Volcanogenic massive sulphide (VMS) deposits are also known as volcanic-associated, volcanic-hosted, and volcano-sedimentary-hosted massive sulphide deposits. They typically occur as lenses of polymetallic massive sulphide that form at or near the seafloor in submarine volcanic environments. They form from metal-enriched fluids associated with seafloor hydrothermal convection. Their immediate h...