A series of heteroleptic titanium derivatives general formula [Ti(OiPr)2(R-acac)2] with acetylacetonate ligands modified in the internal (?- or 3-) position by different substituents (R=OAc, NO2, Me, Et, Cl, Br) has been synthesized and completely characterized liquid multinuclear NMR FTIR. The influence nature group on thermal stability complexes was studied thermogravimetric analysis (TGA) ga...

Four new hetero- and homo-leptic iridium(III) bisterpyridine complexes have been prepared which incorporate aniline (tpy-φ-NH(2)), benzoic acid (tpy-φ-COOH), and benzyl alcohol (tpy-φ-CH(2)OH) substituents at the 4' positions of the tpy ligands (tpy = 2,2':6',2''-terpyridine, φ = phenylene). The electrochemical behaviour and ground and excited state spectroscopic properties of the complexes are...

A series of racemic 2-[(2'-(dimethylamino)biphenyl-2-ylimino)methyl]-4-R(2)-6-R(1)-phenols (L¹H-L⁴H) were reacted with {Mg[N(SiMe3)2]2}2 to provide four heteroleptic magnesium complexes (L¹⁻⁴)MgN(SiMe3)2·(THF)n (1, R(1) = (t)Bu, R(2) = Me, n = 1; 2, R(1) = R(2) = CMe2Ph, n = 0; 3, R(1) = CPh3, R(2) = (t)Bu, n = 1; 4, R(1) = Br, R(2) = (t)Bu, n = 0), which have been fully characterized. X-ray st...

This article reports the synthesis and optical properties of three dinuclear, cationic copper complexes [Cu(2)(μ-dppm)(2)(μ-L)](NO(3))(2) (dppm diphenyldiphosphinomethane, L: L(A) 3,6-bis(2-pyridyl)-4,5-diphenyl-pyridazine, L(B) 3,6-bis(2-pyridyl)-4,5-di(4-pyridyl)-pyridazine and L(C) 3,6-bis(2-pyridyl)-8,9-diazafluoranthene). These were formed on the reaction of [Cu(μ-dppm)(NO(3))](2) with a s...