Due to their unique structure, the optical and mechanical properties graphene and its derivatives (e.g. graphene oxide, reduced graphene oxide) have captured the attention of a constantly increasing number of scientists with regards to biomolecule sensing. This mini review focuses on one specific type of sensor, that consisting of graphene and polyelectrolytes. Polyelectrolyte-graphene nanocomp...

The development of nanostructured composites made metal–organic frameworks (MOFs) and graphene-based components, including exfoliated nanoplates graphene oxide (GO) or reduced (rGO) oxide, is an area great interest in gas storage separation. To improve the industrial viability, it commonly demanded to build these nanocomposites with shape compact units, such as monoliths, foams, pellets, films....

We perform molecular dynamics simulations to investigate the Poisson's ratio of graphene oxide. We find that the Poisson's ratio can be effectively tuned by increasing the degree of oxidation of graphene oxide. More specifically, the Poisson's ratio decreases linearly from positive to negative with increasing oxidation, turning negative at room temperature for a degree of oxidation of 0.27, and...

We report here a new voltammetric method for the sensitive and selective determination of Hg(2+) based on rational covalent functionalization of graphene oxide with cysteamine to form cysteamine-functionalized graphene through nucleophilic ring-opening reaction between the epoxy of graphene oxide and the amino group of cysteamine in KOH solution.

using the computational methods, the interaction effect of tyrosine amino acid on graphene wasinvestigated. for this purpose, the density functional theory (dft) in the ground state of 6-31gwas used, and the interaction effects of tyrosine on graphene was investigated through attachmentto three different base positions. different parameters such as energy levels, the amount ofchemical shift in ...

Graphene-oxide (GO) flakes have been deposited to bridge the gap between two epitaxial-graphene electrodes to produce all-graphene devices. Electrical measurements indicate the presence of Schottky barriers at the graphene/graphene-oxide junctions, as a consequence of the band gap in GO. The barrier height is found to be about 0.7 eV, and is reduced after annealing at 180 degrees C, implying th...

We report an optical study of charge transport in graphene. Diffusion of hot carriers in epitaxial graphene and reduced graphene-oxide samples are studied using an ultrafast pump-probe technique with a high spatial resolution. Spatiotemporal dynamics of hot carriers after a pointlike excitation are monitored. Carrier-diffusion coefficients of 11 000 and 5500 cm2 s−1 are measured in epitaxial gr...

Iron oxide nanostructures (IONs) in combination with graphene or its derivatives-e.g., graphene oxide and reduced graphene oxide-hold great promise toward engineering of efficient nanocomposites for enhancing the performance of advanced devices in many applicative fields. Due to the peculiar electrical and electrocatalytic properties displayed by composite structures in nanoscale dimensions, in...

Of late, graphene has occupied the attention of almost all researchers working globally in the area of materials science. Graphene nanocomposites are the latest additions to the wonder applications of graphene. One of the promising applications of the graphene-oxide nanocomposites is chemical sensing which is useful for monitoring the toxicity, inflammability, and explosive nature of chemicals....

A novel clinical glucose biosensor fabricated using functionalized metalloid-polymer (silver-silica coated with polyethylene glycol) hybrid nanoparticles on the surface of a graphene oxide nanosheet is reported. The cyclic voltammetric response of glucose oxidase modification on the surface of a functionalized graphene oxide electrode showed a surface-confined reaction and an effective redox po...