The photogeneration of X2 is the key to achieving an efficient HX-splitting photocycle, as it more thermodynamically and kinetically challenging than its H2 half reaction counterpart. Here we report a strategy that enables Cl2 photoelimination from low-valent binuclear d9–d9 d9–d10 Ni complexes. We demonstrate importance metal–metal bond interaction for M–X photoactivation with combination TD-D...

Curriculum development and empirical research in the field of second language acquisition could benefit critical pedagogy (CLP) its practitioners. This article reviews central concepts organization curriculum CLP compares them with another major curricular initiative teaching, namely task-based or task-supported approaches, particular emphasis on teaching. Content itself (as activities material...

Abstract Wild boars ( Sus scrofa ) are notorious for accumulating high contamination levels of 137 Cs in their meat. Publicly available data wild from 2011 to 2019 were used determine some radioecological characteristics Germany (affected by Chernobyl-fallout, 1986) and Japan Fukushima, 2011). The effective half-life boar meat was much longer (7.3 y) than (2.6 y), respectively. thus show more p...

The essay illustrates Quaini’s inputs to the construction and theoretical/operational development of territorialist school and, later on, Territorialist Society, which he was one major founders guarantors. In his explication concepts like place, territory, landscape, place awareness, Quaini anticipates need for a multidisciplinary lexicon. Taking from Herodote Italia focus on fundamental integr...

Abstract We analyze stakeholder management (STM) relative to cooperation and individualism within the fourth industrial revolution (FIR). STM is a recent corporate governance tool boosting allowing representativeness of individualistic behaviors even in dialectical environments. Though forerunning it, cooperatives massively use now, while FIR demands also at non-cooperative enterprises. reach t...

The expansion from material heritage – pleasing sight and to a lesser extent touch (for very often may be touched only within limits) the realm of intangible indicates an increase in reflexive consideration full sensorium. With ratification 2003 Intangible Heritage Convention, we have turned select for status cultural practices perceptions entailing body senses more fully: music dance, as well ...

Chinese campuses have been remarkably calm since the post-1989 repression. Yet, absence of contention masks profound changes in party-state’s campus management tactics, exemplifying different approaches authoritarian regimes employ to regiment students. Based on fieldwork before and after Xi Jinping’s rise power (2012), we analyse move from a ‘corporatist’ ‘partification’ strategy campus. Contr...