A protocol for adjusting fusion enthalpies as a function of temperature is described. The protocol combines two simple relationships previously proposed to adjust sublimation and vaporization enthalpies with temperature. This new protocol provides improved accuracy and precision relative to the other theoretical and empirical methods tested. Experimental fusion and vaporization enthalpies measu...

Abstract The Gibbs energy Δ G kp ( τ , T ) of kink pair formation on screw dislocations in bcc Nb has been determined as a function shear stress at different temperatures ⩽ 100 K using an accelerated molecular dynamics method and bond-boost potential. From ), the dependence entropy enthalpy could be obtained standard thermodynamic relations. increases with increasing stress, following phenomeno...

antioxidants are compounds which can prevent biological and chemical substances from oxidative damage by reactive oxygen species. flavonoids are the most important class of polyphenolic compounds that because of their antioxidant characters possess biological activities and pharmacological effects. chrysin-6-c-fucopyranoside and chrysin-3-malonyl-6-c-fucopyranoside are mono c-glycosyl derivativ...

The calculation of the standard enthalpies of vaporization, sublimation and solvation of organic molecules is presented using a common computer algorithm on the basis of a group-additivity method. The same algorithm is also shown to enable the calculation of their entropy of fusion as well as the total phase-change entropy of liquid crystals. The present method is based on the complete breakdow...

The thermal denaturation of aspartate transcarbamoylas of Escherichia coli was investigated by differential scanning calorimetry. Isolated regulatory and catalytic subunits were heat denatured at 55 and 80 degrees C, respectively. In contrast, the intact enzyme was denatured in two steps. A small endotherm near 73 degrees C was assoicated with denaturation of the regulatory subunits and the maj...

The present work concerns with an investigation on the solubility of cis,cis-muconic acid dissolution in different polar solvents by characterizing and modeling the dissolution as a function of temperature. Water, ethanol, 2-propanol and acetic acid have been investigated as solvents in the range temperatures from a 298.15 to 348.15 K. Owing to the absence of cis,cis-muconic acid solubility...