Rhodococcus sp. strain IGTS8 possesses an enzymatic pathway that can remove covalently bound sulfur from dibenzothiophene (DBT) without breaking carbon-carbon bonds. The DNA sequence of a 4.0-kb BstBI-BsiWI fragment that carries the genes for this pathway was determined. Frameshift and deletion mutations established that three open reading frames were required for DBT desulfurization, and the g...

Since the sulfur specific cleavage is vital for the organic sulfur removal from fossil fuel, we explored potential bacterial strains of MTCC (Microbial Type Culture Collection) to desulfurize the Dibenzothiophene (DBT) through C-S bond cleavage (4-S pathway). MTCC strains Rhodococcus rhodochrous (3552), Arthrobacter sulfureus (3332), Gordonia rubropertincta (289), and Rhodococcus erythropolis (...

The main aim of this study was to purify Catechol 1, 2 dioxygenase from phenol utilizing Rhodococcus sp. NCIM 2891 which is basically an organism used wide for desulfurization purposes like desulfurization of diesel. The organism was cultivated in minimal medium supplemented with 500 mg/L phenol, as a sole carbon source. The temperature of incubation was 30oC at pH 7.0±0.2. The growth and pheno...

The performance of a power generation process is most often evaluated in terms of energy efficiency and emissions. Emissions generated by coal-fired power generation are among the main sources of pollution (CO2, dust and acid gases) in China and other coal-intensive countries worldwide. However, this is only the downstream aspect of a coal plant performance, where focus is most often placed on ...

In this study, to simulate a biogas desulfurization process, a modified Monod-Gompertz kinetic model incorporating a dissolved oxygen (DO) effect was proposed for a sulfur-oxidizing bacterial (SOB) strain, Acidithiobacillus thiooxidans, under extremely acidic conditions of pH 2. The kinetic model was calibrated and validated using experimental data obtained from a bubble-column bioreactor. The ...

A considerable amount of Hg is retained in flue gas desulfurization (FGD) gypsum from Wet Flue Gas Desulfurization (WFGD) systems. For this reason, it is important to determine the species of Hg in FGD gypsum not only to understand the mechanism of Hg removal by WFGD systems but also to determine the final fate of Hg when FGD gypsum is disposed. In this study, Temperature Programmed Decompositi...

Effects of magnetic fields on improving mass transfer in flue gas desulfurization with a fluidized bed are investigated in the paper. In this research, the magnetically fluidized bed (MFB) is used as the reactor in which ferromagnetic particles are fluidized with simulated flue gas under the influence of an external magnetic field. Lime slurry is continuously sprayed into the reactor. As a cons...

Phenethylisothiocyanate (PEITC), a naturally occurring isothiocyanate and potent cancer chemopreventive agent, works by multiple mechanisms, including the inhibition of cytochrome P450 (P450) enzymes, such as CYP2E1, that are involved in the bioactivation of carcinogens. PEITC has been reported to be a mechanismbased inactivator of some P450s. We describe here the possible mechanism for the ina...

Temperature programmed decomposition was used to identify mercury (Hg) species in gypsum samples produced from flue gas desulfurization in two Spanish power stations (A and B). As stricter emission control/reduction policies, particularly those focusing on Hg, are being implemented, wet flue gas desulfurization (FGD) technologies used for the removal of SO2 can result in the co-removal of highl...

Different strains of Thiobacillus ferrooxidans and Thiobacillus thiooxidans were used to catalyze the oxidative dissolution of iron pyrite, FeS(2), in nine different coal samples. Kinetic variables and parametric factors that were determined to have a pronounced effect on the rate and extent of oxidative dissolution at a fixed Po(2) were: the bacterial strain, the nitrogen/phosphorus molar rati...