A new polymeric copper complex, viz. catena-poly[[[mu-N,N'-bis(3-aminopropyl)oxamidato-kappa6N,N',O:N",N"',O']dicopper(II)]-di-mu-dicyanamido-1:1'kappa2N1:N5;2:2'kappa2N1:N5], [Cu2(C8H16N4O2)(C2N3)2]n or [Cu(oxpn)0.5[N(CN)2]]n [where H2oxpn is N,N'-bis(3-aminopropyl)oxamide], has been synthesized by the reaction of Cu(oxpn), [Cu(ClO4)2].6H2O and NaN3. In the crystal structure, the Cu atom is fi...

Activated oxygen intermediates during copper zinc superoxide dismutase (SOD) catalysis were investigated using an isotope fractionation technique and natural abundance reagents. Competitive oxygen kinetic isotope effects (KIEs) are reported for the enzyme-catalyzed disproportionation of superoxide as well as the stoichiometric reaction of reduced SOD with molecular oxygen. Analysis within the c...

Biomolecular complexes are often multimers fueling the demand for methods that allow unraveling their composition and geometric arrangement. Pulse electron paramagnetic resonance (EPR) spectroscopy is increasingly applied for retrieving geometric information on the nanometer scale. The emerging RIDME (relaxation-induced dipolar modulation enhancement) technique offers improved sensitivity in di...

degradation of acrylic water base color from synthetic wastewater by the fenton process was performed. experiments were conducted on the sample containing 100 and 400 mg/l of acrylic water base color. the study was performed for searching optimum values of feso4 and h2o2 concentration, ph and temperature. the h2o2 requirement seems to be related to initial cod of the sample. feso4/ h2o2 ratios ...

degradation of acrylic water base color from synthetic wastewater by the fenton process was performed. experiments were conducted on the sample containing 100 and 400 mg/l of acrylic water base color. the study was performed for searching optimum values of feso4 and h2o2 concentration, ph and temperature. the h2o2 requirement seems to be related to initial cod of the sample. feso4/ h2o2 ratios ...

In the title compound, [Cu(CH3COO)2(C9H8N2O)2] n , the CuII ion resides on a centre of inversion, displaying a tetra-gonally distorted octa-hedral coordination environment defined by two pairs of N and O atoms of symmetry-related 4-(1H-imidazol-1-yl)phenol ligands and the O atoms of two symmetry-related acetate ligands. The bridging mode of the 4-(1H-imidazol-1-yl)phenol ligands is associated w...

High-energy-resolution-fluorescence-detected X-ray absorption near-edge structure (HERFD-XANES) spectroscopy is shown to be a sensitive tool to investigate the electronic changes of copper complexes induced by geometric distortions caused by the ligand backbone as a model for the entatic state. To fully exploit the information contained in the spectra gained by the high-energy-resolution techni...

Then cuIi = 0. Hence every c -̂Ii = 0, Ji = L44. But Ii is free of At. Hence h = Ö, I = 0, £ = 0. THEOREM. Every linear covariant of q± is a linear function ofL,A4L,KL. Next, let co > 1. After subtracting from C a constant multiple of qJJ*", whose leader is b^u, we have d = 0 in S. Express S± as a polynomial in c^, cw, fei, and call p the coefficient of their product. The coefficient of c^Cis in...