The most basic assumption of the classical nucleation theory (CNT) is to treat nucleus/liquid surface energy, r, as a macroscopic property having a value equal to that of a planar interface, r1. Therefore, when the CNT is used to analyze experimental data, the size dependence of surface energy is often neglected. To date, there has been no reliable method to measure the surface energy of the nu...

In macromolecular cryocrystallography unit-cell parameters can have low reproducibility, limiting the effectiveness of combining data sets from multiple crystals and inhibiting the development of defined repeatable cooling protocols. Here, potential sources of unit-cell variation are investigated and crystal dehydration during loop-mounting is found to be an important factor. The amount of wate...

The desired bioavailability and the method of drug administration and delivery can require stringent control on the crystal size distribution. Optimal control strategies are proposed to manufacture crystals with a targeted size distribution by combining controlled seeding by impinging jet crystallization with a batch crystallizer operating at a controlled constant growth rate. The same strategi...

We report beaming and enhanced transmission of electromagnetic waves by use of surface corrugated photonic crystals. The modes of a finite-size photonic crystal composed of dielectric rods in free space have been analyzed by the plane-wave expansion method. We show the existence of surface propagating modes when the surface of the finite-size photonic crystal is corrugated. We theoretically and...

transparent glasses in a system of li2o-mgo-sio2-al2o3-fchemical constituents were prepared by melt quenching method. in the fabrication of nanocrystal glass-ceramics, controlled nucleation and subsequent crystal growth were necessary to avoid loss of transparency. it was therefore important to understand thermal properties and crystallization kinetics of the glass ceramics. the crystallization...

In this study, a comprehensive view of a model crystal formation in a complex fluctuating medium is presented. The model incorporates Gaussian curvature effects at the crystal boundary as well as the possibility for super-diffusive motion near the crystal surface. A special emphasis is put on the finite-size effect of the building blocks (macroions, or the aggregates of macroions) constituting ...

The removal of crystal violet from aqueous solution by NiFe2O4 magnetic nanoparticles treated with sodium dodecyl sulfate was investigated. The modified magnetic nanoparticles were prepared by chemical reaction of a mixture of Ni+2 and Fe+3 ions mixture in aqueous solution at the presence of ammonia and then sodium dodecyl sulfate was utilized as an ionic surfactant to modified the obtained mag...

a new polymorph crystalline silica composition having uniform pore dimensions were synthesized by calcining a crystalline hydrated alkyl-ammonium silicate. the pore dimensions approximately were 6 angstrom for silicalite-1 and 11 angstrom for silicalite-2 units. the silicalite-1 was prepared hydrothermally at a ph of about 10 from a reaction mixture consist of water, amorphous silica and a quat...

In a previous paper (1) it was shown that discrimination against strontium as compared to calcium, in the formation of synthetic hydroxyapatite, Calo(POJ)6(OH)2, was greater in large, more slowly grown crystals than in small, more rapidly precipitated crystals. The exclusion of strontium as compared to calcium in the hydroxyapatite crystals increases as the preparation conditions approach equil...