Trace measurements of the element chromium (Cr) are of interest in a wide range of applications and matrices. In the environment, Cr exists in two different oxidation states, the trivalent Cr(III) cation and hexavalent Cr(VI) anion. In mammals, Cr(III) is an essential element involved in the regulation of glucose; however, the element in its hexavalent form demonstrates mutagenic and carcinogen...

This paper investigated the effectiveness of incorporating zero-valent iron (ZVI) into electrokinetic (EK) to remediate hyper-Cr(VI) contaminated clay (2497 mg/kg). A ZVI wall was installed in the center of the soil specimen and was filled with 1:1 (w/w) ratio of granular ZVI and sand. Results show that transport of H(+) is greatly retarded by the strong opposite migration of anionic chromate i...

A resistant and capable fungal strain in removing hexavalent chromium was isolated from an environment near of Chemical Science Faculty, located in the city of San Luis Potosí, Mexico. The strain was identified as Paecilomyces sp., by macro- and microscopic characteristics. Strain resistance of the strain to high Cr (VI) concentrations and its ability to reduce chromium were studied. When it wa...

Acrylonitrile (AN) and 1-vinyl imidazole (VI) based hydrogel was prepared in bulk (macro) dimensions via redox polymerization technique. Afterward, this quaternized (positively charged) exposed to the amidoximation reaction. The hydrogels (quart-p(AN-co-VI), amid-p(AN-co-VI) p(VI)) characterized using fourier transform infrared spectroscopy (FT-IR) thermal gravimetric analysis (TGA). Swelling e...

a microporous bisphenol a diglycidyl ether (dgeba) epoxified-polyethersulfone (pes) blend membrane (epes membrane) was prepared through dry-wet phase inversion. this study attempts to correlate the changes in membrane physical and chemical properties when the epes membranes were exposed to different durations of dry-phase inversion, towards the separation efficiency of carcinogen chromium (vi)....

Chromium (Cr) has been extensively used in many industrial applications. Inappropriate disposal of effluent led to increased Cr concentrations the environment. As a result, Cr(VI) classified under strict control measures by most national and international lists highly toxic materials. Bioremediation Cr(VI)-contaminated effluents appears be more economical environment-friendly treatment method. ...

Bismuth hollow nanospheres were successfully synthesized via a facile solvothermal method and exhibit highly efficient Cr(VI) removal capacities in a wide pH range (2-11).

An alomina-based nano adsorbent was prepared by modification of the external surface of γ-alumina (γ-Al2O3) nanoparticles with functional groups of a new Schiff base 4-[(2-hydroxy-3-methoxy-benzylidene)-amino]-5-methyl-2,4-dihydro-[1,2.4]triazole-3-thione] “L”. In order to the removal of Cr(VI) from aqueous solutions, we used the reaction of the sodium dodecyl sulfate coated nano-alumina with L...

The catalytic properties of various metal nanoparticles have led to their use in environmental remediation. Our aim is to develop and apply an efficient bioremediation method based on in situ biosynthesis of bio-Pd nanoparticles and hydrogen. C. pasteurianum BC1 was used to reduce Pd(II) ions to form Pd nanoparticles (bio-Pd) that primarily precipitated on the cell wall and in the cytoplasm. C....

The extraction of cellulose from sisal fiber was done initially using the steam explosion method. Extracted cellulose was grafted with acrylic acid in the presence of ceric ammonium nitrate redox initiator. The grafting phenomenon taking place between cellulose and the acrylic acid was proved by Fourier transform infrared spectroscopy (FTIR). The prepared graft copolymer was used as adsorbent f...