The reaction of CH3O2 radicals with acetaldehyde on the solid surface of NH4NO3 has been studied in a flow capillary reactor at low pressure and room temperature. The experiments were performed using EPR spectrometer combined with the kinetic method of radicals freezing. Peroxy radicals revealed an oscillation complex behavior during the process regarding to the phenomenon of radicals multiplic...

Trinuclear rare-earth-metal methylidene (CH2 2−) complexes are an emerging class of compounds that serve as methylidene transfer agents for methylenation of carbonyl compounds. Herein, the reaction of a trinuclear scandium methylidene complex with acetophenone was used as a model reaction of the multimetallic-cooperating methylidene transfer case, and its detailed mechanism has been investigate...

We report the synthesis of free 1,6,7,12-tetraazaperylene (tape). Tape was obtained from 1,1'-bis-2,7-naphthyridine by potassium promoted cyclization followed by oxidation with air. Mono- and dinuclear ruthenium(II) 1,6,7,12-tetraazaperylene complexes of the general formulas [Ru(L-L)(2)(tape)](PF(6))(2), [1](PF(6))(2)-[5](PF(6))(2), and [{Ru(L-L)(2)}(2)(μ-tape)](PF(6))(4), [6](PF(6))(4)-[10](PF...

Odontomas are the most common odontogenic tumors. They are broadly classified in to Compound Odontoma and Complex Odontoma. Among them complex odontoma is a rare tumor. Occasionally this tumor becomes large, causing expansion of bone followed by facial asymmetry. Otherwise these tumors are asymptomatic and are generally diagnosed on radiographic examination. We report a rare case of complex odo...

Introduction: Due to the cell labeling potentials of various metal-maltol complexes, the idea of developing a possible cell labeling imaging agent using single photon emission computed chromatography (SPECT) with[111In]-maltolate complex has been investigated. Methods: [111In] labeled 3-hydroxy-2-methyl-4H-pyran-4-onate ([111In]-maltolate) was prepared using f...

the reaction of barium chloride with 2, 6-pyridinedicarboxylic acid in water led to the formation of a novelpolymeric complex formulated as {[ba2(hpydc)2(pydc)(h20)3].h20.(h2pydc)}.(i). the crystal structure of (i)was characterized by single crystal x-ray diffraction method. the complex was crystallized in the monoclinicsystem with space group p2/c, with four molecule in unit-cell, e.g z=4. the...

the present work reports and discusses the results of a 3d simulation of the injection molding process of a rubber compound that includes the mold flling stage and  material curing, using the computer code is developed in “udf” part of the fluent 6.3 cae software. the data obtained from a rheometer (mdr 2000) is used to characterize the rubber material in order to fnd the cure model parameters ...

In the current study, synthesis and characterization of a new nano-structured zirconium(IV)-minoxidil complex (1), where minoxidil, (C9H15N5O; 6-(1-Piperidinyl)-2,4-pyrimidinediamine 3-oxide), have been investigated in two different solvents. The compound 1 has been synthesized by sonochemical method in the presence of methanol and monoethylene glycol (MEG) as solvents and characterized by scan...