We report a sono-Fenton strategy to mediate the supramolecular assembly of metal–phenolic networks (MPNs) as substrate-independent coatings using phenol and phenyl derivatives building blocks. The process is initiated from generation hydroxyl radicals (.OH) high-frequency ultrasound (412 kHz), while metal ions synergistically participate in production additional .OH for hydroxylation/phenolatio...

The sand termite Psammotermes allocerus is widely distributed in southern Africa. To investigate the genetic diversity of this species 113 samples were collected arid regions South Africa, Namibia and Angola fairy circles also landscapes without circles. mitochondrial markers COI COII selected to perform Bayesian Inference analysis. phylogenetic tree composed eight well-supported groups within ...

Two A2B cobalt triaryl corroles bearing ester (1) or carboxylic acid group (2) at the 10-para-phenyl were prepared and used as homogeneous electrocatalysts for hydrogen evolution reaction (HER) with acetic water proton sources. CV results revealed HER underwent two routes [CoIII–H]– (EECC pathway) [CoII–H]2– (ECEC intermediates low concentration. While mainly went through ECEC route high The tu...