Increasing atmospheric levels of CO2, in large part due to anthropogenic combustion of energy yielding hydrocarbons, portends significant if not catastrophic weather related events. One strategy to stabilize atmospheric CO2 levels is to capture the post-combustion product for disposal or, preferably, commercial use. The latter case, in particular, requires the development of both effective and ...

The present study aimed to investigate the feasibility of blended amine absorbents in improving CO2 alkanolamine-based absorption multicycle integrated absorption–mineralization (multicycle IAM) under standard operating conditions (20–25 °C and 1 atm). Multicycle IAM is a promising approach that transforms emissions into valuable products such as carbonates using solvents waste brine. Previousl...

the solubility of co2 in the primary, secondary, tertiary and sterically hindered amine aqueous solutions at various conditions was studied. in the present work, the modified kent-eisenberg (m-ke), the extended debye-hückel (e-dh) and the pitzer models were employed to study the solubility of co2 in amine aqueous solutions. two explicit equations are presented to evaluate the concentration of h...

Sensing of gases is a promising area for applications of photonic systems operating in the mid-infrared spectral range. We present an infrared evanescent-field absorption gas sensor based on a silicon strip waveguide, which was specifically designed for CO2 sensing. We discuss finite element simulations that were used to design the strip waveguide and furthermore present experimental data of qu...

Mass selected cations of Ag clusters are deposited, together with Ar seeded with CO2 (or other electron scavengers such as O2, N2O, or CCl4), on a cold substrate, while being flooded with low energy electrons. Optical absorption measurements reveal an efficient trapping of Ag cluster cations in the Ar matrix, provided that CO2 or another electron scavenger is present to ensure charge neutrality...

A 2-micron pulsed, Integrated Path Differential Absorption (IPDA) lidar instrument for ground and airborne atmospheric CO2 concentration measurements via direct detection method is being developed at NASA Langley Research Center. This instrument will provide an alternate approach to measure atmospheric CO2 concentrations with significant advantages. A high energy pulsed approach provides highpr...

In this research, the thermodynamics and mass transfer of CO2 absorption has been studied in a mixture of MDEA-MEA amines. A relation is presented for mass transfer flux in the reactive-absorption process. For this purpose, the effective parameters on the mass transfer flux were investigated in both liquid and gas phases. Then, using dimensional analysis with the Pi-Buckingham theorem, the effe...