This paper describes a technique for achieving a compact aqueous spray that incorporates CO2 into the spray at low temperatures (T < 10 °C) and high pressures (P > 10 MPa). A high-pressure spray apparatus was used to explore the effects of temperature (4-25 °C), nominal CO2 mole fraction (0-0.12), in-line filter pore size (0.5-7 μm), and additives on the high-pressure (12-19 MPa) water spray pa...

We consider lattice dynamics methods for calculation of the free energy of clathrate hydrate phases, specifically the cubic structure I (sI), cubic structure II (sII), and hexagonal structure H (sH) phases, in the absence of guest molecules; water molecules are modeled with the TIP4P potential. We examine in particular the effects of finite size and proton disorder on the calculated free energi...

Methane hydrate dissociation at negative temperatures was studied experimentally for different artificial and natural samples, differing by macro- and micro-structural parameters. Four characteristic dissociation types are discussed in the paper. The internal kinetics of artificial granule gas hydrates and clathrate hydrates in coal is dependent on the porosity, defectiveness and gas filtration...

[1] Fresh gully-like features on Mars strongly suggest that fluid flowed on the surface in the recent past. Here we consider the possibility that CO2 vapor-supported flows formed the gullies. We find that neither condensed CO2 nor CO2 clathrate hydrate are likely to accumulate in significant quantities in the Martian crust. In addition, if condensed CO2 were present under lithostatic pressures,...

Using a volumetric technique, a T-P diagram of phase transformations between the hydrogen-rich clathrate hydrate (sII phase), hydrogen-filled ice II (C(1) phase), and the liquid (L) is studied in the H(2)O-H(2) system at pressures up to 4.7 kbar and temperatures from -22 to +15 degrees C. The volume and entropy effects of these transformations are established in the vicinity of the triple point...

Gas hydrates have attracted significant fundamental and applied interests due to their important role in various technological environmental processes. More recently, gas shown potential applications for greenhouse capture storage. To facilitate the latter application, introducing chemical additives into clathrate could help enhance hydrate formation/growth rates, provided storage capacity is n...