the hydrogen abstraction reaction of oh radical with ch3ch2ocf2chf2 (hfe-374pc2) is investigated theoretically by semi-classical transition state theory. the stationary points on the potential energy surface of the reaction are located by using kmlyp density functional method along with 6-311++g(d,p) basis set. vibrational anharmonicity coefficients, xij, required for semi-classical transition ...

analysis of the stresses, displacements, and horizontal strains of the ground subsidence due to underground excavation in rocks can be accomplished by means of a hybridized higher order indirect boundary element/finite difference (be/fd) formulation. a semi-infinite displacement discontinuity field is discretized (numerically) using the cubic displacement discontinuity elements (i.e. each highe...

Kemp RB. Effect of the removal of cell surface sialic acid on aggregation in vitro. Nature 1968;218: 1255. 8Steinhardt RA, Lundin L, Mazia D. Bioelectric responses of the echinoderm egg to fertilisation. Proc Natl Acad Sci 1971;68:2426-30. 9 Macieira-Coelho A, Avrameas S. Modulation of cell behaviour in vitro by the substratum in fibroblastic and leukaemic mouse cell lines. Proc Natl Acad Sci 1...

in recent years, the relationship between insertion and deletion (indel) polymorphisms in promoter region (23 bp) and intron 1 (12 bp) of prnp gene (prion protein coding gene) and their relationship to susceptibility of classical bovine spongiform encephalopathy (bse) have been reported. insertions of these two polymorphisms increase resistance to classical bse, while the deletions of these two...

A simple drop method for quantitative urine culture was developed and tested in comparison with standard methods for bacterial urinary counts. In a group of 452 urines all yielding Escherichia coli, 74 showed counts of more than 100,000 colonies, and 16 showed counts between 10,000 and 100,000 colonies per ml. Of these 90 urines, 3 of the 16 in the doubtful group were false negative with the dr...

an efficient and simple method for the preparation of si-imidazole-hso4 functionalized magnetic fe3o4 nanoparticles (si-im-hso4 mnps) and used as an efficient and reusable magnetic catalysts for the regioselective ring opening of epoxides under green conditions in water. this catalyst was used for the ring opening of epoxide corresponding to the thiocyanohydrins and azidohydrines. compared to t...

distinct target of this paper is development of 'implicit discrete element method (dem)' in three dimensions for estimating the ultimate bearing capacity of shallow foundations on layered (non-homogeneous) soils consisting of sand overlying sand or clay overlying sand and vice versa with different shear resisting parameters. in this method, shear resisting parameters and density of ea...