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The mechanism of charge transport through Nafion polymers coated on glassy carbon electrodes and containing Cp2FeTMA+, R~(bpy),~+, and O~(bpy),~+ (where Cp2FeTMA+ is [(trimethylammonio)methyl]ferrocene, bpy = 2,2'-bipyridine) is described. The apparent diffusion coefficients, Dam,, of polymer modified electrodes, as measured by conventional electrochemical methods and which can include contribu...

Many important biologically active compounds contain quaternary carbon centers. Efficient asymmetric syntheses of these compounds represent a significant challenge in organic chemistry.1 Some catalytic synthetic methods directed toward this problem include prolinecatalyzed aldol reactions,2 Michael additions,3 alkylations with phase-transfer catalysts,4 palladium-catalyzed allylations,5 Heck re...

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Synthesis and characterization of V2O3 nanorods Alexander C. Santulli, Wenqian Xu, John B. Parise, Liusuo Wu, M.C. Aronson, Fen Zhang, Chang-Yong Nam, Charles T. Black, Amanda L. Tiano and Stanislaus S. Wong, Phys. Chem. Chem. Phys., 2009 DOI: 10.1039/b822902c Flame spray-pyrolyzed vanadium oxide nanoparticles for lithium battery cathodes See-How Ng, Timothy J. Patey, Robert Büchel, Frank Krume...

ATP has two significant effects on the mitochondrial tricarboxylate transporting system. First, it alters the concentration gradients at equilibrium for the substrates of this transporter. ATP (2 IDM) caused the uptake of 10 nmol of citrate into the mitochondria coincident with the output of a similar amount of L-malate. This redistribution was dependent on ATP transport, the effect being inhib...