A series of cadmium carboxylate compounds in a sulfur-rich environment provided by the tris(2-tert-butylmercaptoimidazolyl)hydroborato ligand, namely, [Tm(Bu(t))]CdO2CR, has been synthesized via the reactions of the cadmium methyl derivative [Tm(Bu(t))]CdMe with RCO2H. Such compounds mimic aspects of cadmium-substituted zinc enzymes and also the surface atoms of cadmium chalcogenide crystals, a...

In this study the levels of cadmium and lead in blood and urine were measured by the method of graphite furnace atomic absorption spectrometry in 356 healthy, non-occupationally exposed individuals and the factors affecting the metal concentrations were investigated. The geometric means for cadmium in blood and urine were 0.98 microg/l (Cd-B) and 0.87 microg/gCr (Cd-U). The lead levels were 32....

The reaction of ArPO(3)H(2) (Ar = 2,4,6-iPr(3)-C(6)H(2)) with Cd(CH(3)COO)(2).2H(2)O using various co-ligands such as methanol, dimethylformamide (DMF) and 3,5-dimethylpyrazole (DMPZH) resulted in the formation of tetranuclear assemblies [Cd(4)(ArPO(3))(2)(ArPO(3)H)(4)(CH(3)OH)(4)].3(CH(3)OH) (1), [Cd(4)(ArPO(3))(2)(ArPO(3)H)(4)(DMF)(4)].3(DMF) (2) and [Cd(4)(ArPO(3))(2)(ArPO(3)H)(4)(DMF)(2)(DM...

Pollution of the aquatic environment by heavy metals has become a worldwide problem. Most heavy metals exhibit toxic waste on aquatic organisms. Cadmium (Cd) is a highly toxic metal which affects aquatic organisms acutely and chronically. Planktonic calanoid copepods are the secondary dominant producers of pelagic ecosystems and play a considerable role in the transfer of energy and organic mat...

Human prostate carcinoma cell line DU-145 was used to examine the relationship between the intracellular levels of cysteine-rich metallothi onein (MT) and the sensitivity or resistance of cells to Adriamycin (ADR). The basis for the poor response of human prostate carcinomas to ADR was studied. Cadmium-resistant (Cdr) cells, capable of growth in Kl 5 M cadmium, were derived from DU-145 cadmium-...

We have previously shown that cadmium (Cd) and benzo[a]pyrene (BaP) induced early DNA damages in zebra mussels, and that the level of DNA strand breaks (SB) returned to a basal level after 3 days of exposure to Cd. The aim of the present study was to go further in the mechanisms of Cd and BaP detoxification. For that purpose, expression of genes encoding for metallothionein (MT), aryl hydrocarb...

A cadmium-tolerant population of Chlamydomonas reinhardtii was derived from a Cd-sensitive cell wall-deficient strain by long-term selection in liquid culture. A comparison of Cd-sensitive and Cd-tolerant cells revealed that Cd tolerance was due to genetically determined alterations of metabolism rather than to increased efficiency of a detoxification system.

The aim of these experiments was to apply magnesium (50 and 100 mg Mg kg soil) to neutralise the potentially negative effects of soil contamination by cadmium (10, 20, 30 and 40 mg Cd kg soil) on the number of some groups of microorganisms. Another objective was to determine the relationship between the number of these microorganisms relative to yield of yellow lupine and some physicochemical p...

The biosorption characteristics of Cd (II) ions using the living biomass of the marine diatom Phaeodactylum tricornutum were investigated. This microalga is a highly tolerant species to cadmium toxicity; for this reason, it is interesting to know its potential for use in the removal of this metal. The use of living biomass offers better possibilities than that of dead biomass since cadmium can ...

introduction: with increasing of population and the valuable water resource pollutions, a demand has been felt for new and inexpensive methods in order to remediation and improving of water quality. cadmium is a trace element. in low concentration, this heavy metal is harmful to life, and considered as a dangerous pollutant. cadmium leads to pollution and reduction of water quality; sometimes e...