the purpose of this reaserch is to measure the phase equilibrium data of the ternary system (water + phosphoric acid + 1-nonanol) at different temperatures. experimental solubility curves and tie-line points for the system were obtained at t = 298.2, 308.2 and 318.2 k and ambient pressure. the binodal curve data were detected by the cloud point method. the mass fractions of each layer were achi...

The present article serves the purpose of pursuing Geometrization of heat flow on volumetrically isothermal manifold by means of RF approach. In this article, we have analyzed the evolution of heat equation in a 3-dimensional smooth isothermal manifold bearing characteristics of Riemannian manifold and fundamental properties of thermodynamic systems. By making use of the notions of various curva...

in order to preparing strontium ion selective electrode 6-(4- nitropheny1)-2-pheny14, 4- dipropy1-3, 5-diaza-bicyclo [3, 1, 0] hex-2-ene (npdbh) was used as an ionophore. this electrode responds to sr (ii)ion with a sensitivity of 28.2 ± 0.5 mv/decade over the range 1.0 x 10-6 to 1.0 mat ph 3.0-10.0. thelimit of detection was 2.4 x 10-7 m. the influences of membrane composition, the ph of the t...

The local thermodynamics of a system with long-range interactions in d dimensions is studied using the mean-field approximation. Long-range interactions are introduced through pair interaction potentials that decay as a power law in the interparticle distance. We compute the local entropy, Helmholtz free energy, and grand potential per particle in the microcanonical, canonical, and grand canoni...

We developed a multistep thermodynamic perturbation method to compute the interfacial free energies by nonequilibrium work measurements with cleaving potential procedure. Using this method, we calculated the interfacial free energies of different crystal orientations for the Lennard-Jones system. Our results are in good agreement with the results by thermodynamic integration method. Compared wi...

Adaptive resolution schemes allow the simulation of a molecular fluid treating simultaneously different subregions of the system at different levels of resolution. In this work we present a new scheme formulated in terms of a global Hamiltonian. Within this approach equilibrium states corresponding to well-defined statistical ensembles can be generated making use of all standard molecular dynam...

This paper describes a consistent set of thermodynamic properties and transport coefficients for different gases and gas mixtures depending on temperature and pressure. The species thermochemical properties have been computed directly from their partition functions. Atomic and molecular energy levels have been incorporated up to 50.000 K avoiding extrapolation of the JANAF data. Equlibrium part...