A convenient synthesis of (6R,7S)-(+)-himachala-9,11-diene, the pheromone of the chrysomelid beetle Phyllotreta striolata is described. The diene is obtained in a single operation by a spontaneous “bromination/dehydrobromination” of 2,6,6,9-tetramethylbicyclo[5.4.0]undec-8-ene. The halogenation/dehalogenation sequence proceeds spontaneously in CCl4, and is less uniform in CH2Cl2 and CHCl3. H NM...

The tunable photo-induced electronic property of the Cs2[{Mo6Bri8}Bra6] and Br2[{Ta6Bri12}(H2O)a6] octahedral metal cluster-based compounds was characterized by zeta potential measurement upon irradiation ultraviolet–visible (UV–Vis) light. enhancement charge on surface [{Mo6Bri8}Bra6]2- anion caused increased negative potential. Both showed dependence as a function light excitation. This will ...

This paper reports, for the first time, the nonlinear optical property of β-HgBrCl, which was synthesized by a reaction of Hg2Cl2 and Br2 in EtOH. This reaction also gave α-HgBrCl. And the single crystal structures of both α- and β-HgBrCl are presented and compared. β-HgBrCl shows phase-matchable powder second harmonic generation (SHG) effect of about 2 times that of KH2PO4 (KDP). Its absorptio...

Abstract: We provide, with proofs, a complete description of the authors’ construction of state-sum invariants announced in [CY], and its generalization to an arbitrary (artinian) semisimple tortile category. We also discuss the relationship of these invariants to generalizations of Broda’s surgery invariants [Br1,Br2] using techniques developed in the case of the semi-simple sub-quotient of Re...

Photoelectrochemical cells (PECs), composed of different epitaxial n-Si photoanodes coated with evaporated metal film of Ni, Pt, Ni/Pt and immersed in solution with redox couple Br2 /Br or Fe(NC)g~7Fe(CN)£~ were investigated. The open circuit photovoltage and short circuit current density of these PECs under optimum conditions by illuminating with a bromine-tungsten lamp (65 mW/cm), are 0.494 V...

Rotationally resolved infrared spectra are reported for halogen atom-HF free radical complexes formed in helium nanodroplets. An effusive pyrolysis source is used to dope helium droplets with Cl, Br and I atoms, formed by thermal dissociation of Cl2, Br2 and I2. A single hydrogen fluoride molecule is then added to the droplets, resulting in the formation of the X-HF complexes of interest. Analy...

The newly developed lifting collocation penalty (LCP) formulation for conservation laws is extended to solve the Navier-Stokes equations on 2D mixed meshes. The LCP formulation is an extension of the flux reconstruction (FR) method. Like the FR method, it can unify several popular high order methods including the discontinuous Galerkin and the spectral volume methods into a more efficient diffe...

Origins of CD bands in lima bean proteinase inhibitor were deduced from an acetylation-deacetylation study of the sole tyrosyl residue in the protein (Tyr 69), and by analogy with Bowman-Birk soybean proteinase inhibitor, a homologous protein with similar spectral properties. Tyr 69 is relatively inaccessible to N-acetylimidazole; 100-fold molar excess of the reagent in the presence of 6 M guan...