A stable mu-nitrido diiron phthalocyanine activates H2O2 to oxidize CH4 in water at 25-60 degrees C to methanol, formaldehyde and formic acid as evidenced using 13C and 18O labelling.

In this study, a bioremediation approach was evaluated for the decontamination of an aquifer affected by release organohalides industrial landfill. After preliminary physicochemical and microbiological characterization landfill groundwater, stimulation natural organohalide respiration addition reducing substrate (i.e., molasse) tested both at microcosm field scales, placement anaerobic permeabl...

The discovery of oxygen and carbon monoxide tolerant [NiFe] hydrogenases was the first necessary step toward the definition of a novel generation of hydrogen fed biofuel cells. The next important milestone is now to identify and overcome bottlenecks limiting the current densities, hence the power densities. In the present work we report for the first time a comprehensive study of herringbone ca...

This study reports the kinetics and mechanism of Fe(III)-catalyzed oxidative decarboxylation and deamination of a series of acyclic (α-aminoisobutyric acid, α-(methylamino)isobutyric acid, alanine, norvaline, and 2-aminobutyric acid) and cyclic (1-aminocyclopropane-1-carboxylic acid, 1-amino-1-cyclobutanecarboxylic acid, 1-aminocyclopentanecarboxylic acid, and 1-aminocyclohexanecarboxylicacid) ...

Microbial nitrate-dependent Fe(II) oxidation is known to contribute to iron biogeochemical cycling; however, the microorganisms responsible are virtually unknown. In an effort to elucidate this microbial metabolic process in the context of an environmental system, a 14-cm sediment core was collected from a freshwater lake and geochemically characterized concurrently with the enumeration of the ...

Adsorption of heavy metals and radionuclides (HMR) onto iron and manganese oxides has long been recognized as an important reaction for the immobilization of these compounds. However, in environments containing elevated concentrations of these HMR the adsorptive capacity of the iron and manganese oxides may well be exceeded, and the HMR can migrate as soluble compounds in aqueous systems. Here ...

Liquid fuels like dimethyl-ether (DME), produced from biomass and electricity are crucial for decarbonizing the shipping industry. In this work, production of DME wheat straw through gasification is presented. It was shown how process can be optimized by using 1) two-stage instead one-stage synthesis, 2) partial oxidation gas 3) a hydrogen quench high-temperature reverse water shift reactions. ...

first row transition metal complexes of phthalocyanine are employed as catalysts for the oxidation of cyclohexene and cyclooctene using iodosylbenzene and pentafluoroiodosyl benzene. the catalysis was performed in dichloromethane: methanol:water (80:18:2) solvent mixture.  the products of the catalysis for cyclohexene are epoxycyclohexane, 2-cyclohexene-1-ol and 2-cyclohexene-1-one whereas for ...

Herein, a systematic study of a series of molecular iron model complexes has been carried out using Fe L2,3-edge X-ray absorption (XAS) and X-ray magnetic circular dichroism (XMCD) spectroscopies. This series spans iron complexes of increasing complexity, starting from ferric and ferrous tetrachlorides ([FeCl4]-/2-), to ferric and ferrous tetrathiolates ([Fe(SR)4]-/2-), to diferric and mixed-va...

three hundred twin births from a hospital in tehran, iran have been analyzed for seasonal variation at birth and physical measurements. the results show that the highest twinning rates for mm (5.61), ff (7.73) and mf (5.36) were seen in april, january and september, respectively. the four physical measurements at birth showed non-significant differences among the male and female twins, but mm a...