Chemical oscillations in the classic Belousov-Zhabotinsky (BZ) system typically have a period of a few minutes, which can be increased significantly by changing the organic substrate. Here we show that by changing the temperature and concentrations, an increase of 3-4 orders of magnitude in the frequency of BZ oscillations can be obtained. At elevated temperatures, in high concentration mixture...

We discuss a model for the autocatalytic reaction A + B → 2A on substrates where the reactants perform a compact exploration of the space, i.e., on lattices whose spectral dimensioñ d is < 2. For finite systems, the total time τ for the reaction to end scales according to two different regimes, for high and low concentrations of reactants. The functional dependence of τ on the volume of the sub...

Experiments with the 1,4-cyclohexanedione Belousov-Zhabotinsky reaction demonstrate that three-dimensional scroll waves can rotate around filaments that end in the wake of a traveling excitation pulse. The vortex structures nucleate during the collision of three nonrotating excitation pulses. The nucleation process and the wave-termination of filaments are direct consequences of the system's an...

We found a rotating global structure induced by the dynamical force of local chemical activity in a thin solution layer of excitable Belousov-Zhabotinsky reaction coupled with diffusion. The surface flow and deformation associated with chemical spiral waves (wavelength about 1 mm) represents a global unidirectional structure and a global tilt in the entire Petri dish (100 mm in diameter), respe...

The field of self-organization in nonequilibrium chemical systems comprises the study of dynamical phenomena in chemically reacting systems far from equilibrium. Systematic exploration of this area began with investigations of the temporal behavior of the Belousov-Zhabotinsky oscillating reaction, discovered accidentally in the former Soviet Union in the 1950s. The field soon advanced into chem...

Several reaction-diffusion systems that exhibit temporal periodicity when well mixed also display spatio-temporal pattern formation in a spatially distributed, unstirred configuration. These patterns can be travelling (e.g. spirals, concentric circles, plane waves) or stationary in space (Turing structures, standing waves). The behaviour of coupled and forced temporal oscillators has been well ...

In a reverse microemulsion consisting of water, oil (octane), an anionic surfactant [aerosol OT (AOT)], and the reactants of the oscillating Belousov-Zhabotinsky (BZ) reaction, a variety of complex spatiotemporal patterns appear. These include traveling and standing waves, spirals that move either toward or away from their centers, spatiotemporal chaos, Turing patterns, segmented waves, and loc...