نتایج جستجو برای: arrhenius parameter

تعداد نتایج: 217707  

Journal: :The Journal of chemical physics 2012
Vasile Iulian Clapa Tsampikos Kottos Francis W Starr

We analyze the structure of instantaneous normal modes (INM) associated with the Hessian matrix of a liquid. Utilizing a scaling theory developed in the framework of Anderson localization studies, we unambiguously identify the crossover point in the INM spectrum between extended and localized modes. We establish a relation between the unstable, delocalized INMs and the liquid diffusion coeffici...

Journal: :Proceedings of the National Academy of Sciences of the United States of America 1971
J K Raison J M Lyons

Lipids of mitochondrial membranes from hepatic cells of active ground squirrels apparently go through a phase change induced at approximately 23 degrees C similar to the phase change in mitochondria of homeotherms. This change was indicated by the activity of succinate oxidase from the isolated mitochondria exhibiting a nonintersecting discontinuous Arrhenius plot. This discontinuity in the Arr...

2006
Kirsten Martens D. L. Stein A. D. Kent

We present a theory of magnetization reversal due to thermal fluctuations in thin submicron-scale rings composed of soft magnetic materials. The magnetization in such geometries is more stable against reversal than that in thin needles and other geometries, where sharp ends or edges can initiate nucleation of a reversed state. The two-dimensional ring geometry also allows us to evaluate the eff...

Journal: :Physical review. E, Statistical, nonlinear, and soft matter physics 2001
L Roters S Lübeck K D Usadel

We analyze numerically a moving interface in the random-field Ising model which is driven by a magnetic field. Without thermal fluctuations the system displays a depinning phase transition, i.e., the interface is pinned below a certain critical value of the driving field. For finite temperatures the interface moves even for driving fields below the critical value. In this so-called creep regime...

2009
U. Hagelauer

The catalytic activity and activation energy of an enzyme are obtained by measuring the rate of the enzymic reaction at two different temperatures. With the aid of the Arrhenius equation, these two parameters can be used to calculate a value proportional to the quantity of enzyme. Using this approach to investigate the isoenzymes of creatine kinase, it was shown that the activation energy incre...

پایان نامه :وزارت علوم، تحقیقات و فناوری - دانشگاه فردوسی مشهد - دانشکده علوم 1375

in chapter one we will describe definitions and preliminary results to provide the global context of our own results to be presented in detail in the subsequent chapters in chapter two we consider degree-one maps of the circle and we study their rotation set. our main result in this chapter says that if the map is topologically mixing then its rotation interval is nontrivial (that is, not reduc...

Journal: :Journal of The Taiwan Institute of Chemical Engineers 2021

Emerging applications in nanomaterials processing are increasingly featuring multiple physical phenomena including magnetic body forces, chemical reactions and high temperature behavior. Stimulated by developing a deeper insight of nanoscale fluid dynamics such manufacturing systems, the current article, we study nanofluid along nonlinear porous stretching sheet with Arrhenius kinetics wall tra...

Journal: :The Journal of biological chemistry 1966
V Massey B Curti H Ganther

~-Amino acid oxidase has been shown to have a critical temperature of 12-14’. Around this temperature it has been shown that a reversible change in protein conformation occurs; the change in enthalpy of the transition has been calculated as 78,000 cal per mole. Other parameters have also been shown to change on either side of this temperature; these include sedimentation constant, ultraviolet a...

2005
R. Edgardo Catalan

The activities of acetylcholinesterase (ACHE) and butyrylcholinesterase (BuChE) in rat brain capillaries were measured as a function of temperature. Arrhenius plots of the data revealed that AChE exhibits a biphasic Arrhenius plot with a distinct break (transition temperature) at about 15.2 kcal/mol. In contrast, BuChE did not show evidence of discontinuity. BuChE showed an activation energy hi...

2001
GIANCARLO FRANZESE

We consider a frustrated spin model with a glassy dynamics characterized by a slow component and a fast component in the relaxation process. The slow process involves variables with critical behavior at finite temperature Tp and has a global character like the (structural) α-relaxation of glasses. The fast process has a more local character and can be associated to the β-relaxation of glasses. ...

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