The recognition of small molecules in hydrophobic cavities aqueous medium is a fundamental process molecular biology. Previously, we described the synthesis and conformational switching enantiopure alleno-acetylenic cage receptors as well their application model systems to study detail interplay space occupancy, conformation, complexation, chiral organic solvents. Now, report three functionaliz...

Low concentrations of fluoride (F−) in drinking water are beneficial for oral health, but the natural occurrence high F− content has been reported various groundwater sources, posing a continuous ingestion threat to humans. The utilization biochar (BC) produced from residual biomass emerged as technically, economically, and environmentally sustainable alternative removal through adsorption. The...

The ingenious combination of lactate and diethylenetriamine-N,N,N’,N”,N”pentaacetic acid (DTPA) as an aqueous actinide-complexing medium forms the basis of the successful separation of americium and curium from lanthanides known as the TALSPEAK process. While numerous reports in the prior literature have focused on the optimization of this solvent extraction system, considerably less attention ...