UNLABELLED The development of bioactive phosphate-based glasses is essential in biomaterials science, and especially for bone substitution applications. In this context, the preparation of amorphous calcium-phosphorus hydroxide/oxide monoliths at low temperature is a key challenge for being able to develop novel hybrid materials for these applications. We herein report for the first time the sy...

AIM To determine if the addition of inert fillers to a bioactive dental restorative composite material affects its degree of conversion (DC), polymerization shrinkage (PS), and microhardness (HV). METHODS Three amorphous calcium phosphate (ACP)-based composite resins: without added fillers (0-ACP), with 10% of barium-glass fillers (Ba-ACP), and with 10% of silica fillers (Si-ACP), as well as ...

The aim of this in vitro study was to compare the shear bond strength (SBS) and failure modes of a conventional resin-based composite with a recently developed amorphous calcium phosphate (ACP)-containing orthodontic composite system. Forty freshly extracted human maxillary premolar teeth were randomly divided into two equal groups. Conventional composite (group 1; Transbond-XT; 3M Unitek) and ...

The feasibility of calcium carbonate cements involving the recrystallisation of metastable calcium carbonate varieties has been demonstrated. Calcium carbonate cement compositions presented in this paper can be prepared straightforwardly by simply mixing water (liquid phase) with two calcium carbonate phases (solid phase) which can be easily obtained by precipitation. An original cement composi...

We are familiar with large highly-ordered single crystals, such as those used in the semiconductor industry. There the crystalline ordering in the silicon crystals extends for billions and more lattice spacings. As a result, X-ray diffraction (XRD) patterns of these crystals have sharp Bragg peaks. We are also familiar with liquids, where the molecules have a local structure that is very differ...

Chlorapatite can be considered a potential biomaterial for orthopaedic applications. Its use as plasma-sprayed coating could be of interest considering its thermal properties and particularly its ability to melt without decomposition unlike hydroxyapatite. Chlorapatite (ClA) was synthesized by a high-temperature ion exchange reaction starting from commercial stoichiometric hydroxyapatites (HA)....

The aim of this study was to evaluate effect of bleaching agents on sound enamel (SE) and enamel with early artificial caries lesions (CL) using confocal laser scanning microscopy (CLSM). Eighty blocks (4 x 5 x 5 mm) of bovine enamel were used and half of them were submitted to a pH cycling model to induce CL. Eight experimental groups were obtained from the treatments and mineralization level ...

Because of its relatively high solubility in aqueous media and its rapid transformation to hydroxyapatite, amorphous calcium phosphate (ACP) has been utilized as the filler phase of resin-based bioactive composites that have remineralization potential. The objectives of this study were to determine how various methacrylate resins and various types of ACP fillers affect acrylic vinyl conversion ...

Calcium phosphate based glasses with different concentrations of TiO2 (0 to 2.5 mol%) were prepared and their corresponding glass-ceramics were obtained by controlled heat treatments. The amorphous nature of glasses and the presence of crystalline phases in glass-ceramics were studied through XRD studies. Density, molar volume, ultrasonic velocities, attenuation, elastic constants and microhard...