Li 2-3x Al x S (0 ≤ 0.1667) was prepared via the planetary ball-milling method. Diffuse reflection UV-Vis measurements revealed that band gap and electronic structure of 2 changed with formation defective S. Compared = 0, ionic conductivity for sample 0.1334 improved by ∼3 orders magnitude. The lithium movement activation energy pre-exponential factor A were found to be dependent on value. S, a...

Abstract Lithium phosphorus oxygen nitrogen (LiPON) as solid electrolyte discovered by Bates et al in the 1990s is an important part of all-solid-state thin-film battery (ASSTFB) due to its wide electrochemical stability window and negligible low electronic conductivity. However, ionic conductivity LiPON about 2 × 10 −6 S cm −1 at room temperature much lower than that other types electrolytes, ...

Abstract While all-solid-state batteries have built global consensus with regard to their impact in safety and energy density, anode-less versions attracted appreciable attention because of the possibility further lowering cell volume cost. This perspective article summarizes recent research trends (ALASSBs) based on different types solid electrolytes anticipates future directions these may tak...