The paper describes a signal method for processing GC-MS signals to extract usable information hidden in the chromatogram thus reducing the labour and time required to handle the data and increasing the quality and objectivity of the results. The method is focused on two relevant parameters for identification and characterization of the n-alkane series present in complex samples (in particular ...

Fungal lignocellulolytic enzymes are promising agents for oxidizing pollutants. This study investigated degradation of Number 6 "Bunker C" fuel oil compounds by the white-rot fungi Irpex lacteus, Trichaptum biforme, Phlebia radiata, Trametes versicolor, and Pleurotus ostreatus (Basidiomycota, Agaricomycetes). Averaging across all studied species, 98.1%, 48.6%, and 76.4% of the initial Bunker C ...

Cayley's theorem, in principle, can be used in determining the isomers of alkanes lot, which was originally limited to the calculation of the number of isomers of manual calculation, the method of "drawing and counting." Graph structure of the alkane is a tree (the tree). By proving that the alkane is a tree graph of a satisfying E (G) = V (G) with a value of V (G) = 3n + 2 and E (G) = 3n +1, -...

2014 The effects of mixed phospholipid headgroup composition and the addition of small amounts of alkane were examined with respect to the lamellar (L03B1) to inverse hexagonal (HII) phase transition in phospholipidwater liquid crystals. X-ray diffraction was used to probe the lattices and determine the phases. It has been postulated that competition between hydration repulsion, lipid monolayer...

The Deepwater Horizon (DWH) blowout in the northern Gulf of Mexico represents one of the largest marine oil spills. Significant shifts in bacterial community composition in the water column correlated to the microbial degradation and utilization of oil hydrocarbons. Nevertheless, the full genetic potential and taxon-specific metabolisms of bacterial hydrocarbon degraders enriched during the DWH...

Alkane monooxygenases in Nocardioides sp. strain CF8 were examined at the physiological and genetic levels. Strain CF8 can utilize alkanes ranging in chain length from C(2) to C(16). Butane degradation by butane-grown cells was strongly inhibited by allylthiourea, a copper-selective chelator, while hexane-, octane-, and decane-grown cells showed detectable butane degradation activity in the pre...

Decades of research on the autooxidation of organic compounds have provided fundamental and practical insights into these processes; however, the structure of many key autooxidation intermediates and the reactions leading to their formation still remain unclear. This work provides additional experimental evidence that highly oxygenated intermediates with one or more hydroperoxy groups are preva...

The atmosphere of Titan, Saturn's largest moon, exhibits interesting UV- and radiation-driven chemistry between nitrogen and methane, resulting in dipolar, nitrile-containing molecules. The assembly and subsequent solvation of such molecules in the alkane lakes and seas found on the moon's surface are of particular interest for investigating the possibility of prebiotic chemistry in Titan's hyd...

We consider the task of filtering the noise from images and other types of inputs which are assumed to be piecewise continuous and piecewise monotone. We show that nonlinear diffusion of the data, a powerful filtering method, is too restrictive for such a case, leading to piecewise constant functions. We claim that the piecewise monotonicity can be enhanced by nonlinear diffusion of first parti...