ZIF-8, a prototypical zeolitic porous coordination polymer, prepared via the self-assembly of tetrahedral atoms (e.g. Zn and Co) and organic imidazolate linkers, presents large cavities which are interconnected by narrow windows that allow, in principle, molecular sieving. However, ZIF-8 shows flexibility due to the swing of the imidazolate linkers, which results in the adsorption of molecules ...

A combination of in situ and ex situ surface plasmon resonance (SPR) imaging experiments is used to characterize the differential electrostatic adsorption of proteins and synthetic polypeptides onto photopatterned monolayers at gold surfaces. The nonspecific electrostatic adsorption of proteins onto negatively charged self-assembled monolayers (SAMs) of 11-mercaptoundecanoic acid (MUA) is found...

This paper reports a study of the adsorption of four proteins-fibrinogen, lysozyme, pyruvate kinase, and RNAse A-to self-assembled monolayers (SAMs) on gold. The SAMs examined were derived from thiols of the structure HS(CH2)loR, where R was CH3, CHzOH, and oligo(ethy1eneoxide). Monolayers that contained a sufficiently large mole fraction of alkanethiolate groups terminated in oligo(ethy1eneoxi...

This random sequential model is quite general and versatile, and can be customized to describe a variety of two-state physical systems that exhibit adsorption and evaporation processes. One-dimensional sequential adsorption models have been studied thoroughly in different physics contexts [17, 34]. Adsorption in two dimensions is not as well understood, however. There are quite a few computatio...

recently, the use of biological absorbent in removal of hazardous pollutants such as heavy metals has increased because of the decrease in sludge problems, economical issues, high efficiency and compatibility with the environment. this study was done over the biosorption of nickel by biosolids obtained from the municipal wastewater treatment in a batch reactor. the pretreatment of the biosolids...

fine particles silicoaluminophosphate-34 were synthesized by hydrothermal sol-gel method. the effect of crystallization time, as one of the important synthesis factors on particle size and crystallinity, kinetic and equilibrium adsorption, and selectivity of co2 / ch4 has been studied in this work. the adsorption isotherms are obtained at moderate gauge pressures (100-3000 kpa) and temperatures...

Self-assembly of surface-active agents at solid–liquid interfaces is critical for many processes in nature and technology, including the stability of suspension, detergency, wetting and mineral separation. Historically, a detailed understanding of nanometerscale layers has emerged. However, surprisingly little is known about their dynamics—the key to non-equilibrium phenomena. Even in equilibri...

Free-standing poly(vinyl alcohol)/poly(acrylic acid) (PVA/PAA) membranes with polydopamine (PDA) coating were prepared based on the combination of electrospinning and self-polymerization of dopamine. This is a facile, mild, controllable, and low-energy consumption process without any rigorous restriction to reactive conditions. Benefiting from the high specific surface area of electrospun membr...

diagnosing and assessing child abuse is a critical and difficult process in clinical psychology, because this phenomenon has several negative behavioral and psychological consequences on victims. the aim of this research is to create a scale for assessing child abuse and neglect. through a multiclustral sampling, 3042 secondary school students (boys and girls) were selected to fill (1) a list o...

The present article provides current opinion on studies of the interfacial dynamics, adsorption, and structure of surfactant layers. The physical principles and applications of physicochemical methods such as tensiometry, ellipsometry, photon correlation spectroscopy, and neutron reflectivity techniques, as well as relevant theoretical aspects related to the adsorption and desorption kinetics, ...