نتایج جستجو برای: acetylacetone
تعداد نتایج: 451 فیلتر نتایج به سال:
We assess the performance of different protocols for simulating excited-state x-ray absorption spectra. consider three based on equation-of-motion coupled-cluster singles and doubles, two them combined with maximum overlap method. The differ in choice a reference configuration used to compute target states. Maximum-overlap-method time-dependent density functional theory is also considered. appr...
Two representative Walphos analogues with an achiral 2,2″-biferrocenediyl backbone were synthesized. These diphosphine ligands were tested in the rhodium-catalyzed asymmetric hydrogenation of several alkenes and in the ruthenium-catalyzed hydrogenation of two ketones. The results were compared with those previously obtained on using biferrocene ligands with a C2-symmetric 2,2″-biferrocenediyl b...
A short and efficient total synthesis of the alkaloid isosolenopsin and its enantiomer has been achieved. In the key step, a ω-transaminase catalyzed the regioselective mono-amination of the diketone pentadecane-2,6-dione which was obtained in a single step via Grignard reaction. Initial low conversions in the biotransformation could be overcome by optimisation of the reaction conditions employ...
It is generally supposed that the preconcentration procedure is used for the determination of metal concentrations under the sensitivity of the measurement method. This study showed that preconcentration is also need for the beryllium (Be) concentration over the sensitivity of atomic absorption spectrometry. For this purpose, a simple and selective method for the determination of Be in solid sa...
A model donor-acceptor oligomer consisting of benzodithiophene-diketone and thiophene has been investigated with regard to its molecular packing and opto-electronic properties. The crystal structure suggests that the packing is dominated by charge-transfer interactions between the electron-rich part of the molecule and the electron-poor part. A series of observations corroborate this assumption...
We previously reported the usefulness of a fluorometric method to determine urinary delta-aminolevulinic acid (ALA) concentrations by using post-column derivatization to monitor the effect of lead exposure. We have further improved the method by introducing pre-column derivatization by using reaction of ALA with acetylacetone and formaldehyde. Response of the hematopoietic system to lead exposu...
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