IN THE TITLE COMPOUND (ALTERNATIVE NAME: pyridine-3-carbo-hydrazide, C(6)H(7)N(3)O), the asymmetric unit contains a single mol-ecule. In contrast with nicotinic acid and nicotinamide, the C=O bond is found to be oriented cis with respect to the C(ipso) C N fragment in the pyridine ring. The pyridine ring and the hydrazide group make a dihedral angle of 34.0 (2)°. In the crystal structure, mol-e...

The title heteroaryl chalcone derivative, C17H17NO4, is close to planar: the dihedral angle between the pyridine and benzene rings is 3.71 (11)° and the meth-oxy C atoms deviate from their attached ring by 0.046 (3), -0.044 (2) and 0.127 (3) Å. The disposition of the pyridine N atom and the carbonyl group is anti [N-C-C-O = -177.7 (2)°]. In the crystal, mol-ecules are linked by weak C-H⋯N and C...

In the title mol-ecule, C(12)H(12)N(6), the dihedral angles between the pyridine rings and the central dimethan-imine-hydrazine group are 0.30 (3) and 13.94 (3)°. Two intra-molecular N-H⋯N hydrogen bonds stabilize the planar conformation of one pyridine ring with respect to its hydrazine-residue neighbour, whereas the other pyridine ring and an N-bonded H atom are rotated out of the plane and l...

The title compound, C(19)H(19)N(3)O(4)S(2), was prepared by the reaction of 2,3-diamino-pyridine with tosyl chloride in a mixture of dichloro-methane-pyridine as solvent. In the crystal, mol-ecules associate via pairs of N-H⋯N hydrogen bonds, forming a centrosymmetric eight-membered {⋯HNCN}(2) synthon. The dihedral angles between the amino-pyridine ring and the tosyl benzene rings are 50.01 (6)...

As part of our ongoing antikinetoplastid structure–activity relationship study focused on positions 2 and 8 the 3-nitroimidazo[1,2-a]pyridine scaffold, we were able to introduce a phenylthioether moiety at both position in one step. Using previously reported synthetic route developed laboratory, obtained 6-chloro-3-nitro-8-(phenylthio)-2-[(phenylthio)methyl]imidazo[1,2-a]pyridine 74% yield. The...

Metal hydrazine, pyridine–2-carboxylate hydrates, pyridine–3-carboxylate hydrates, [ML(N2H4)0.5.H2O] where L = pyridine–2-carboxylic acid, pyridine–3-carboxylic acid and M = Co, Ni, Mn and Zn have been prepared and characterized by analytical, IR, UV-Vis and XRD Studies. Thermal decomposition of the compounds is studied from room temperature to 1200C by TG-DTA analysis. The compounds were found...

The pyridine rings of the title compound, C(18)H(23)N(3), are in a nearly perpendicular orientation relative to the plane defined by the three amino-bonded C atoms, making dihedral angles of 87.4 (1) ° and 84.2 (1) °. One of the pyridine N atoms acts as an hydrogen-bond acceptor for two pyridine C-H groups. By means of these intermolecular hydrogen bonds, the mol-ecules form a two-dimensional n...

In the title compound, C(17)H(17)Cl(2)NO(2), the central 1,4-dihydro-pyridine ring adopts a flattened-boat conformation. The ethanone substituents of the dihydro-pyridine ring at positions 3 and 5 have synperiplanar (cis) or anti-periplanar (trans) conformations with respect to the adjacent C=C bonds in the dihydro-pyridine ring. The 2,4-dichloro-phenyl ring is almost planar [r.m.s. deviation =...

 In this article, synthesis of the explosive 2, 6 (diamino) 3, 5 dinitro pyridine (ANPY) of the direct nitration reaction of 2, 6 diamino pyridine in different conditions of temperature, with density functional theory method were studied. For this purpose, at first the material contained in the both sides of reaction were geometrically optimized, then the calculation of the the...

In the title compound, C(18)H(13)BrN(4)O(3)S(3), the tetra-hydro-pyridine ring adopts a half-chair conformation with the central methyl-ene-C atom of the NCH(2)CH(2) unit at the flap. The dihedral angles between the tetra-hydro-pyridine ring and the pyridine and two thio-phene rings are 69.34 (13) 5.66 (13) and 68.63 (13)°, respectively, while the dihedral angle between the 1,3,4-oxadiazole and...