نتایج جستجو برای: 1 thioamidoalkyl 2 naphthol

تعداد نتایج: 3934074  

Journal: :journal of sciences islamic republic of iran 0

a solid chelating material, 1-(2-pyridy1azo)-2-naphthol (pan) supported on naphthalene provides a rapid and highly selective means of preconcentration of uranium from aqueous solution. uranium is quantitatively retained on this adsorbent in the ph range 9.8-10.7 with a flow rate of 1 ml min . the metal complex was desorbed with 10 ml of 2 m hydrochloric acid and uranium is determined by differe...

Journal: :The Analyst 2013
Jiaojiao Luo Cuisong Zhou Yalin Shi Lei Zhang Dan Xiao

Ruthenium nanoparticle tris(2,2'-bipyridyl)ruthenium(II) bis(hexafluorophosphate) (Ru(bpy)3(PF6)2, RuNP) was self-assembled on polystyrene (PS) electrospun microfibers. The formation of RuNP is attributed to the sulfonated PS (SPS) microfibers' high adsorptive capability of 94% for Ru(bpy)3(2+), as well as the strong interaction between the Ru(bpy)3(2+) and ionic liquid (1-butyl-3-methylimidazo...

Ehsan Pakdaman Fatemeh Tavakoli Mohamad Reza Froudi Jahromi, Saideh Bagheri Samira Zandifar

A new kinetic spectrophotometic method for the determination of trace amount Chromium (III) in Teareal samples has been described based on it s the catalytic effect on the oxidations of 1 - ( 2 –PyridylAzo ) - 2 - Naphthol, (PAN), by potassium bromated in sulfuric acid. The reaction is followedspec- trophotometrically by measuring the decrease in the absorbance at 469 nm. Under the optimumcondi...

Journal: :Chemical communications 2016
Anjan Das Tanmay Banerjee Kenneth Hanson

We demonstrate the photocatalytic protonation of a silylenol ether using 7-bromo-2-naphthol as an ESPT catalyst with phenol as the sacrificial proton source. Greater than 95% conversion is achieved with 1 mol% catalyst. The reaction cycle is dependent on the significantly increased acidity of the catalyst in the excited state as well as the long lifetime for the triplet excited state of 7-bromo...

M. R. Froudi Jahromi R. Pour Gholam S. Bagheri S. Zandifar

A new kinetic spectrophotometic method for the determination of trace amount manganese(II) in Tea real samples has been described based on it s the catalytic effect on the oxidations of 1 - (2 – Pyridyl Azo) - 2 - Naphthol, (PAN), by potassium bromated in sulfuric acid. The reaction is followed spectrophotometrically by measuring the decrease in the absorbance at 547.5 nm. Under the optimum con...

Journal: :Journal of the American Chemical Society 2002
Noam Agmon Wolfgang Rettig Christian Groth

We present semiempirical AM1 calculations for the ground and excited state of 2-naphthol and some of its cyano derivatives in the gas phase. Following photoexcitation, the Mulliken electron density on the oxygen diminishes slightly for the acid and more conspicuously for the anionic conjugated base. This agrees with the measured solvatochromic parameters for 2-naphthol. In both electronic state...

2010
De-Ling Li Li-Hong Wang

The title compound, C(25)H(21)ClO(2), was synthesized via the three-component coupling of 4-chloro-benzaldehyde, 2-naphthol and 5,5-dimethyl-cyclo-hexane-1,3-dione. The pyran ring adopts a boat conformation, while the cyclo-hexenone ring is in an envelope conformation. The 4-chloro-phenyl ring is almost perpendicular to the pyran ring [dihedral angle = 87.39 (1)°]. In the crystal, mol-ecules ar...

Journal: :The journal of physical chemistry. A 2011
Mirabelle Prémont-Schwarz Dequan Xiao Victor S Batista Erik T J Nibbering

We investigate the OH stretch vibrational frequency shifts of a prototype photoacid, 2-naphthol (2N), when dissolved in solvents of low polarity. We combine femtosecond mid-infrared spectroscopy and a theoretical model based on the Pullin-van der Zwan-Hynes perturbative approach to explore vibrational solvatochromic effects in the ground S(0) and the first electronically excited (1)L(b) states....

Journal: :Journal of the American Chemical Society 2005
David A Evans Regan J Thomson

The development of a Ni(II) (S)-Tol-BINAP-catalyzed enantioselective alkylation of N-acylthiazolidinethiones with trimethyl orthoformate is described. The reaction is general with respect to the thiazolidinethione, providing the desired adducts in good to excellent yield and with high levels of enantioselectivity (11 examples, 51-92% yield, 90-99% ee). The products are readily converted into a ...

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