Molecular combinatory computing makes use of a small set of chemical reactions that together have the ability to implement arbitrary computations. Therefore it provides a means of “programming” the synthesis of nanostructures and of controlling their behavior by programmatic means. We illustrate the approach by several simulated nano-assembly applications, and discuss a possible molecular imple...

We report on the evolution of a hollow sphere secondary structure of spherical nanoparticles by a solubilization-reprecipitation mechanism based on the difference of solubility products (K(sp)) of two different precipitates. Carbon-coated nanoparticles of olivine structure LiFePO(4) served as the primary nano-blocks to build the secondary nano-architecture.

Star-shaped polymers with varying arm numbers and arm lengths are synthesized, and self-assembled into microspheres, which are either smooth or fibrous on the nanoscale, and either nonhollow, hollow, or spongy on the microscale. The molecular architecture and functional groups determine the structure on both length scales. This exciting mechanistic discovery guides simultaneous control of both ...

A critical view on the outcome of research in nanomaterials for electrochemical energy storage devices (batteries and supercapacitors) is provided through selected examples. The nano- approach traces back to the early battery research and its benefits realized even before the nano- term was coined. It has enabled important progresses which have translated, for instance, in the possibility of us...

Nano-structuring of the surface caused by adsorption of molecules or atoms and by the reaction of surface atoms with adsorbed species are reviewed from a chemistry viewpoint. Self-assembly of adsorbed species is markedly influenced by weak mutual interactions and the local strain of the surface induced by the adsorption. Nano-structuring taking place on the surface is well explained by the noti...

This article reports the development and evaluation of two nano-emulsions (F45T-03/HFB and F15T-03/PFOB) containing fluorinated trityl radicals dissolved in perfluorocarbons. Preparation with a high-pressure homogenizer conferred sub-micronic size to both nano-emulsions. In vitro and in vivo EPR spectroscopy showed that the nano-emulsions had much greater oxygen sensitivity than the hydrophilic...

In the last two decades, nano manipulation has been recognized as a potential tool of scientific interest especially in nanotechnology and nano-robotics. Contemporary optical microscopy (super resolution) techniques have also reached the nanometer scale resolution to visualize this and hence a combination of super resolution aided nano manipulation ineluctably gives a new perspective to the sce...

Sodium nitrite (NaNO(2)) was evaluated in a 55% EBV hemorrhage swine model to mitigate the increased blood pressure due to HBOC-201. Animals were resuscitated by three 10 ml/kg infusions of either HBOC-201 or Hextend with and without NaNO(2). All vital signs, coagulation and blood chemistry were measured for 2 hr. HBOC-201-vasoconstriction was attenuated only after the first 10.8 μmol/kg NaNO(2...

The objective of the project was to fabricate gold nano-rods and study the optical properties of gold nano-particles when coupled to Indium Arsenide quantum dots. The gold nano-rods were synthesized by a seed-mediated growth method using CTAB and BDAC as the surfactants, and the feasibility of changing the aspect ratio of the rods and their Plasmon resonance frequency was studied by varying the...

This study demonstrates the advantages of the combination between atomic force microscopy and scanning electrochemical microscopy. The combined technique can perform nano-electrochemical measurements onto agarose surface and nano-electrografting of non-conducting polymers onto conducting surfaces. This work was achieved by manufacturing an original Atomic Force Microscopy-Scanning ElectroChemic...