There are currently great needs to develop low-cost inorganic materials that can efficiently perform solar water splitting as photoelectrolysis of water into hydrogen and oxygen has significant potential to provide clean energy. We investigate the Si/TiO2 nanowire heterostructures to determine their potential for the photooxidation of water. We observed that highly dense Si/TiO2 core/shell nano...

Indium tin oxide (ITO) and titanium dioxide (TiO2) anti-reflective coatings (ARCs) were deposited on a (100) P-type monocrystalline Si substrate by a radio-frequency (RF) magnetron sputtering. Polycrystalline ITO and anatase TiO2 films were obtained at room temperature (RT). The thickness of ITO (60 to 64 nm) and TiO2 (55 to 60 nm) films was optimized, considering the optical response in the 40...

Titanium dioxide (TiO2) is an important material for photovoltaics, photocatalysis, sensors and lithium ion batteries. Various morphologies of TiO2 nanomaterials have been synthesized, including zero-dimensional (0D) nanoparticles, one-dimensional (1D) nanowires and nanotubes, as well as three-dimensional (3D) nanostructures. But the two-dimensional (2D) TiO2 nanostructures, which are expected ...

The photoelectrochemical (PEC) responses of electron-irradiated 66-phenyl-C61-butyric acid methyl ester (PCBM)/TiO2 electrodes were evaluated in a PEC cell. By coating PCBM on TiO2 nanoparticle film, the light absorption of PCBM/TiO2 electrode has expanded to the visible light region and improved the PEC responses compared to bare TiO2 electrode. The PEC responses were further improved by irrad...

We studied the photocatalytic properties of rational designed TiO2-ZnO hybrid nanostructures, which were fabricated by the site-specific deposition of amorphous TiO2 on the tips of ZnO nanorods. Compared with the pure components of ZnO nanorods and amorphous TiO2 nanoparticles, these TiO2-ZnO hybrid nanostructures demonstrated a higher catalytic activity. The strong green emission quenching obs...

Thin films of titanium dioxide (TiO2) have attracted considerable attention in the past few years, since nanocrystalline TiO2 shows outstanding properties and has widespread application potential. The possible applications range from solar cells and energy conversion systems, gas and UVsensors, battery systems to photocatalysis and self-cleaning surfaces. All these applications rely on the semi...

The objective of the this study was to compare concentrations of nanosized TiO2 at 0, 5, 20, 40, 60 and 80 mg L(-1) with bulk TiO2 for phytotoxic and stimulatory effects on fennel seed germination and early growth stage. After 14 d of seed incubation, germination percentage highly improved following exposure to 60 ppm nanosized TiO2. Similar positive effects occurred in terms of shoot dry weigh...

This study investigates the decomposition of clofibric acid (CLF) by different advanced oxidation processes (AOPs), such as UV (254nm), VUV (185 nm), UV / TiO2 and VUV / TiO2. The removal efficiencies of applied AOPs were compared in the presence and absence of dissolved oxygen. The removal efficiency of the studied AOPs towards degradation of CLF were found in the order of VUV / TiO2 + O2 > VU...

First-principles calculations of anatase structured TiO2 and ZrO2 as well as of TiO2-B were carried up to 20 GPa in order to develop an understanding of the unusual compression and pressure-dependent phase transitions reported for nanocrystalline (nc) pure and Zr-doped anatase and nc TiO2-B. The computations, carried out using two global hybrid density functional-Hartree-Fock formulations and a...